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碳源对反应烧结碳化硅性能的影响

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以炭黑和石墨为碳源,控制碳添加量为10%(质量分数,下同),研究了不同炭黑、石墨比例对反应烧结碳化硅性能的影响.结果表明,当炭黑添加量为4%、石墨添加量为6%时,反应烧结碳化硅的力学性能较佳,此时抗弯强度为251.7 MPa,断裂韧性为4.29 MPa·m1/2.通过XRD检测及对XRD谱进行Rietveld精修,分析发现炭黑添加量为4%、石墨添加量为6%的反应烧结碳化硅中的游离Si含量为24.44%(质量分数),而石墨添加量为10%的反应烧结碳化硅中的游离Si含量为28.57%(质量分数),相比前者游离Si含量较高,减少游离Si的含量可以提高反应烧结碳化硅的力学性能.
Effects of Carbon Sources on Properties of Reaction-Bonded Silicon Carbide
The carbon black and graphite were used as carbon sources to fabricate reaction-bonded SiC,and the total content of carbon sources was 10%(mass fraction,the same below).The effects of different ratios of carbon black and graphite on properties of reaction-bonded SiC were investigated.The results show that the reaction-bonded SiC with 4%carbon black and 6%graphite has good mechanical properties,the flexural strength and fracture toughness reach to 251.7 MPa and 4.29 MPa·m1/2.The mineral composition of reaction-bonded SiC was measured by XRD,the Rietveld simulation results of XRD patterns were adopted to measure phase content.The free Si content in reaction-bonded SiC with 4%carbon black and 6%graphite is 24.44%(mass fraction).The free Si content in reaction-bonded SiC with 10%graphite reaches to 28.57%(mass fraction),which is higher than that of the former.The decrease of free Si contributes to the improvement of mechanical properties of reaction-bonded SiC.

reaction-bonded SiCcarbon blackgraphitemechanical propertyfree Si

张喜飞、陈定、顾华志、黄奥、付绿平

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武汉科技大学省部共建耐火材料与冶金国家重点实验室,武汉 430081

反应烧结碳化硅 炭黑 石墨 力学性能 游离Si

国家自然科学基金国家自然科学基金

5200229552172023

2024

硅酸盐通报
中国硅酸盐学会 中材人工晶体研究院

硅酸盐通报

CSTPCD北大核心
影响因子:0.698
ISSN:1001-1625
年,卷(期):2024.43(1)
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