硅酸盐通报2024,Vol.43Issue(2) :534-542.

磷石膏的综合利用及其在建筑材料领域的应用研究进展

Research Progress on Comprehensive Utilization of Phosphogypsum and Its Application in the Field of Building Materials

周武 李杨 冯伟光 苏轶 揭伟哲 张华 倪红卫
硅酸盐通报2024,Vol.43Issue(2) :534-542.

磷石膏的综合利用及其在建筑材料领域的应用研究进展

Research Progress on Comprehensive Utilization of Phosphogypsum and Its Application in the Field of Building Materials

周武 1李杨 1冯伟光 2苏轶 1揭伟哲 1张华 1倪红卫1
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作者信息

  • 1. 武汉科技大学钢铁冶金与资源利用省部共建教育部重点实验室,武汉 430081;武汉科技大学钢铁冶金新工艺湖北省重点实验室,武汉 430081
  • 2. 青岛睿海兴业管理咨询服务有限公司,青岛 266041
  • 折叠

摘要

磷石膏是湿法制备磷肥工艺过程中的副产物,主要物相是CaSO4·2H2O.我国磷石膏产量居世界第一,综合利用率却不到50%,堆存量已达8亿吨,对生态环境造成了严重破坏,因此,探索磷石膏的有效利用途径已迫在眉睫.本文对磷石膏综合利用主要领域的研究现状进行了分析,其中磷石膏在化工领域的利用率仅有5%,在农业领域的利用率也只有2%,而建筑材料领域是目前磷石膏的主要应用领域.目前将磷石膏应用于水泥缓凝剂、石膏砌块和水泥砂浆已经实现了工业化;将磷石膏应用于胶凝材料和路基材料,由于浸出毒性的问题,并未大规模应用;将磷石膏用作填充剂则因为材料强度较低,仅仅停留于实验室探索阶段.最后展望了未来无害化利用磷石膏技术研究的发展趋势,以期为解决磷石膏的堆存问题提供参考.

Abstract

Phosphogypsum is a byproduct in the wet process of phosphate fertilizer production,with its main phase being CaSO4·2H2O.Despite China being the world's largest producer of phosphogypsum,its comprehensive utilization rate is below 50%.The accumulated stock has reached 800 million tons,causing severe ecological damage.Therefore,exploring effective utilization methods for phosphogypsum is urgently needed.This article analyzes the current research status of the comprehensive utilization of phosphogypsum in various fields.Currently,the utilization rate of phosphogypsum in the chemical industry is only 5%,and in agriculture is a mere 2%,while the building materials sector remains its primary application field.Industrial applications such as using phosphogypsum as a cement retarder,gypsum block,and cement mortar have been industrialized.However,its application in cementitious materials and subgrade materials has not been widely adopted due to concerns about leaching toxicity.The use of phosphogypsum as a filler is still in the experimental exploration phase due to the relatively low strength of material.The paper concludes by envisioning the future trends in the research on environmental friendly utilization of phosphogypsum,aiming to provide references for resolving the stockpile issue of phosphogypsum.

关键词

磷石膏/综合利用/应用领域/建筑材料/研究现状/发展趋势

Key words

phosphogypsum/comprehensive utilization/application field/building material/research status/development trend

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基金项目

国家自然科学基金面上项目(52374344)

出版年

2024
硅酸盐通报
中国硅酸盐学会 中材人工晶体研究院

硅酸盐通报

CSTPCD北大核心
影响因子:0.698
ISSN:1001-1625
被引量2
参考文献量15
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