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三乙醇胺和硬脂酸锌对泡沫混凝土性能的影响

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为解决泡沫混凝土存在的高吸水率问题,本文研究了三乙醇胺(TEA)和硬脂酸锌(ZS)对泡沫混凝土孔隙特征、力学性能和防水性能的影响,同时结合接触角测试仪、扫描电子显微镜-能谱仪和X射线衍射仪等微观分析手段,研究了 TEA和ZS对泡沫混凝土的改性机理.结果表明,加入1.6%(质量分数)TEA和0.4%(质量分数)ZS可以增大泡沫混凝土直径小于500 μm孔隙的占比,使泡沫混凝土 28 d抗压强度提升到1.66 MPa.加入0.4%(质量分数)TEA和1.6%(质量分数)ZS能够将泡沫混凝土 1、2、3 d吸水率降至2.8%、7.9%和10.5%,接触角最高达134.9°,使泡沫混凝土表面呈现疏水特征.TEA和ZS复掺能够增强泡沫在固化水泥浆体中的稳定性,细化孔隙结构,减少连通孔数量,提升泡沫混凝土的力学性能和防水性能.
Effects of Triethanolamine and Zinc Stearate on Properties of Foam Concrete
In order to solve the long-standing problem of high water absorption of foam concrete,the effects of triethanolamine(TEA)and zinc stearate(ZS)on the pore characteristic,mechanical property and waterproof performance of foam concrete were studied.And the modification mechanism of TEA and ZS on foam concrete was studied by contact angle test,scanning electron microscopy with energy spectroscopy and X-ray diffractometer test methods.The results show that the addition of 1.6%(mass fraction)TEA and 0.4%(mass fraction)ZS can increase the proportion of pores with a diameter of less than 500 μm,and increase 28 d compressive strength of foam concrete to 1.66 MPa.The addition of 0.4%(mass fraction)TEA and 1.6%(mass fraction)ZS can reduce the water absorption of foam concrete to 2.8%,7.9%and 10.5%at 1,2,3 d,and the contact angle reaches up to 134.9°,so that the foam concrete has a hydrophobic surface.The co-doping of TEA and ZS can enhance the stability of foam in the solidified cement slurry,refine the pore structure,reduce the number of connecting pores and improve the mechanical property and waterproof performance of foam concrete.

foam concretetriethanolaminezinc stearatepore structuremechanical propertywaterproof performance

李兆睿、王振军、张海宝、张亚明、张松林、张博伦

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长安大学材料科学与工程学院,西安 710061

西安斯派新材料科技有限公司,西安 710600

西安邮电大学理学院,西安 710100

泡沫混凝土 三乙醇胺 硬脂酸锌 孔隙结构 力学性能 防水性能

西安市科技计划陕西省交通科研项目新疆生产建设兵团科技项目

23KGDW0035-202321-53k2021DB005

2024

硅酸盐通报
中国硅酸盐学会 中材人工晶体研究院

硅酸盐通报

CSTPCD北大核心
影响因子:0.698
ISSN:1001-1625
年,卷(期):2024.43(3)
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