硅酸盐通报2024,Vol.43Issue(3) :1030-1038.

CaF2污泥对硅酸盐水泥性能的影响及机理分析

Effect and Mechanism Analysis of CaF2 Sludge on Ordinary Portland Cement

胡川 杨文伟 赵环环
硅酸盐通报2024,Vol.43Issue(3) :1030-1038.

CaF2污泥对硅酸盐水泥性能的影响及机理分析

Effect and Mechanism Analysis of CaF2 Sludge on Ordinary Portland Cement

胡川 1杨文伟 1赵环环2
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作者信息

  • 1. 宁夏大学土木与水利工程学院,银川 750021;宁夏土木工程防震减灾工程技术研究中心,银川 750021
  • 2. 宁夏大学土木与水利工程学院,银川 750021
  • 折叠

摘要

固废利用是实现"双碳"目标的重要途径之一.本文以固废CaF2污泥为水泥掺合料,通过抗压强度、浆体流动度试验探讨了 CaF2污泥掺量对水泥胶凝材料性能的影响,并结合XRD、SEM及TGA-DSC等微观表征测试进行机理分析.结果表明,CaF2污泥的掺加有利于提高水泥胶凝材料的早期强度,CaF2污泥掺量为8%(质量分数)的胶凝材料抗压强度表现较好.CaF2污泥的掺加会导致浆体流动度降低,但掺量低于10%(质量分数)时对浆体流动度影响并不显著,掺量为8%、10%(质量分数)时浆体流动度比未掺加CaF2污泥时降低了 3.0%.CaF2污泥在胶凝材料中主要起物理效应,CaF2污泥能够形成更多的结晶位点,促进水泥水化.CaF2污泥掺量增加使水泥的稀释效应及团聚效应显著.掺量为8%(质量分数)的CaF2污泥复合水泥的微观性能较好.

Abstract

Solid waste utilization is one of the important ways to achieve the goal of"double carbon".Taking solid waste CaF2 sludge as cement admixture,the effect of CaF2 sludge content on the properties of cement cementing material was investigated through compressive strength and slurry fluidity tests,and the mechanism was analyzed by XRD,SEM and TGA-DSC microscopic characterization tests.The results show that the addition of CaF2 sludge can improve the early strength of cement cementing material.The compressive strength of cement cementing material with 8%(mass fraction)CaF2 sludge is better.The addition of CaF2 sludge leads to the decrease of slurry fluidity,but the addition of less than 10%(mass fraction)has no significant effect on slurry fluidity,compared with the cement without CaF2 sludge,the slurry fluidity of the cement with 8%and 10%(mass fraction)CaF2 sludge is reduced by 3.0%.CaF2 sludge mainly plays a physical effect in cementing material,and CaF2 sludge can form more crystallization sites to promote cement hydration.The dilution effect and agglomeration effect of CaF2 sludge to cement increase significantly.The microscopic properties of cement with 8%(mass fraction)CaF2 sludge are better.

关键词

CaF2污泥/水泥/抗压强度/浆体流动度/微观机理

Key words

CaF2 sludge/cement/compressive strength/slurry fluidity/microscopic mechanism

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基金项目

宁夏回族自治区大学生创新创业训练计划(2023)(S202310749136)

出版年

2024
硅酸盐通报
中国硅酸盐学会 中材人工晶体研究院

硅酸盐通报

CSTPCD北大核心
影响因子:0.698
ISSN:1001-1625
参考文献量20
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