首页|Na2O-CaO-SiO2平板玻璃减反射功能化研究

Na2O-CaO-SiO2平板玻璃减反射功能化研究

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随着光伏产业的高速发展,与之配套使用的减反射玻璃重新进入了研究者们的视野.本文采用湿化学二步刻蚀法制备了具有减反射性能的Na2O-CaO-SiO2平板玻璃,采用分光光度计、扫描电子显微镜、原子力显微镜和X射线能谱仪等测试样品的透过率、表面形貌和断面膜层厚度、表面化学成分、耐酸性和硬度,研究了反应温度和反应时间、玻璃膜层结构与透过率的关系.通过使用弱碱性的混合盐溶液对Na2O-CaO-SiO2玻璃表面进行化学刻蚀,使玻璃表面Si—O键断裂,在玻璃表面形成纳米膜层结构,当膜层厚度达到一定厚度时,一定波长的光在玻璃表面发生相消干涉,透过率最高可达到97.8%,刻蚀前后玻璃成分基本无变化,铅笔硬度达到3H.
Anti-Reflection Functionalization of Na,O-CaO-SiO2 Flat Glass
With the rapid development of photovoltaic industry in recent years,anti-reflective glass comes into researchers'sight.This article uses two-step chemical etching method to prepare Na2O-CaO-SiO2 flat glass with anti-reflective properties.The transmittance,surface morphology,cross-section film thickness,surface chemical composition,acid resistance and hardness of samples were measured by spectrophotometer,scanning electron microscope,atomic force microscope and X-ray energy spectrometer.The relationship between reaction temperature,reaction time,glass film structure and transmittance were studied.The Si—O bonds on Na2O-CaO-SiO2 flat glass surface were broken by etching glass surface with weakly alkaline mixed salt solution,and a nano film structure is formed on the surface of glass.When the corrosion reaches a certain thickness,destructive interference of a certain wavelength of light occurs on glass surface,with a maximum transmittance of 97.8%.The glass composition remains basically unchanged before and after etching,and the pencil hardness reaches 3H.

anti-reflection glasstransmittanceNa2O-CaO-SiO2 flat glasswet chemical two-step etching methodsurface micro-crackcrack extension

郝霞、王其琛、符有杰、李军葛、赵会峰、姜宏、王卓

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海南海控特玻科技有限公司,澄迈 571924

海南大学,海南省特种玻璃重点实验室,海口 570100

山东轻工职业学院,淄博 255000

减反射玻璃 透过率 Na2O-CaO-SiO2平板玻璃 湿化学二步刻蚀法 表面微裂纹 纳米孔

海南省重大科技计划

ZDKJ2021049

2024

硅酸盐通报
中国硅酸盐学会 中材人工晶体研究院

硅酸盐通报

CSTPCD北大核心
影响因子:0.698
ISSN:1001-1625
年,卷(期):2024.43(4)
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