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纳米C-S-H/PCE对蒸养UHPC力学性能增强机理研究

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目前超高性能混凝土(UHPC)制品的力学性能有待进一步提升,采用纳米C-S-H/PCE对UHPC进行增强在理论上是一种可行的技术途径。本文研究了蒸养条件下掺入以聚羧酸(PCE)为分散剂的纳米水化硅酸钙(C-S-H/PCE)对UHPC力学性能的影响,通过测试水化热、水化产物、微观形貌和孔结构等对其机理进行了分析。结果表明,掺入3。0%(质量分数)纳米C-S-H/PCE可以显著提高蒸养UHPC的抗压强度和抗折强度。掺入纳米C-S-H/PCE可以促进UHPC的早期水化,生成更多的水化硅酸钙(C-S-H)凝胶,使水化放热温峰增高,并缩短达到水化温峰的时间。掺入纳米C-S-H/PCE可有效改善蒸养UHPC的孔结构,在掺量为 3。0%(质量分数)时总孔隙率最小,有害孔比例最低。该研究可为纳米C-S-H/PCE在蒸养UHPC中的应用提供参考。
Enhancement Mechanism of Mechanical Properties of Steam-Cured UHPC by Nano-C-S-H/PCE
At present,the mechanical properties of ultra-high performance concrete(UHPC)products need to be further improved,and the use of nano-C-S-H/PCE to enhance UHPC is a feasible technical way in theory.The effect of nano-C-S-H/PCE on the mechanical properties of UHPC under steam-cured condition was studied.The influence mechanism was analyzed by measuring hydration heat,hydration products,microstructure and pore structure.The results show that the incorporation of 3.0%(mass fraction)nano-C-S-H/PCE significantly increases compressive and flexural strengths of steam-cured UHPC.The addition of nano-C-S-H/PCE can promote the hydration in early age of UHPC and form more C-S-H gel,and increase the exothermic temperature peak of hydration and shorten time to reach the hydration temperature peak.Also,the pore structure of steam-cured UHPC can be improved effectively by adding nano-C-S-H/PCE,and the total porosity and harmful pore proportion are the lowest at 3.0%(mass fraction)nano-C-S-H/PCE.This study can provide a theoretical reference for the application of nano-C-S-H/PCE in steam-cured UHPC.

nano-C-S-H/PCEUHPCpore structurehydration heatsteam-curing

伍勇华、易昂、何娟、匡玉峰、原毅冰

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西安建筑科技大学材料科学与工程学院,西安 710055

纳米C-S-H/PCE 超高性能混凝土 孔结构 水化放热 蒸汽养护

陕西省自然科学基础研究计划项目

2021JM-353

2024

硅酸盐通报
中国硅酸盐学会 中材人工晶体研究院

硅酸盐通报

CSTPCD北大核心
影响因子:0.698
ISSN:1001-1625
年,卷(期):2024.43(8)