硅酸盐通报2024,Vol.43Issue(8) :3017-3025.

MgAlON-Al2O3复相陶瓷的热压烧结制备及性能

Preparation and Properties of MgAlON-Al2O3 Composite Ceramics by Hot Pressing Sintering

徐勇 靖正阳 陈浩 陈博文 涂兵田 王皓
硅酸盐通报2024,Vol.43Issue(8) :3017-3025.

MgAlON-Al2O3复相陶瓷的热压烧结制备及性能

Preparation and Properties of MgAlON-Al2O3 Composite Ceramics by Hot Pressing Sintering

徐勇 1靖正阳 1陈浩 1陈博文 1涂兵田 1王皓1
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作者信息

  • 1. 武汉理工大学材料复合新技术国家重点实验室,武汉 430070;武汉理工大学襄阳示范区湖北隆中实验室,襄阳 441000
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摘要

MgAlON与α-Al2O3 的光学折射率相近,两种材料构成的复相陶瓷有望在保持较好光学性能的同时获得优化的显微结构及机械和热性能.本研究基于Van-de-Hulst理论对MgAlON-Al2O3 复相陶瓷的光学透过行为进行预测,发现其理论直线透过率随α-Al2O3 含量降低和晶粒尺寸减小而增大,且在波长为2μm处达86%.在热压烧结制备的复相陶瓷中,α-Al2O3 通过晶界钉扎效应有效抑制了MgAlON晶粒的长大.随着烧结温度升高,复相陶瓷中的α-Al2O3 含量下降,陶瓷的光学透过率上升,机械性能和热导率降低.1 500~1 650℃烧结的 1mm厚样品在波长为4μm处的最大直线透过率大于72.6%.其中,1 600℃烧结样品的最大直线透过率为76.1%,弹性模量为321.69 GPa,硬度为15.93 GPa,四点抗弯强度为 268.09 MPa,断裂韧性为 2.41 MPa·m1/2,热导率为13.98 W·m-1·K-1.

Abstract

MgAlON and α-Al2O3 have comparable optical refractive indices,and the composite ceramics composed of two materials are expected to obtain optimized microstructures,mechanical and thermal properties while maintaining reasonable optical properties.In this study,the optical transmittance behavior of MgAlON-Al2O3 composite ceramics were predicted based on Van-de-Hulst theory,and it is found that the theoretical in-line transmittance increases with the decrease of content and grain size of α-Al2O3,and it can reach 86%at the wavelength of 2 μm.In the composite ceramics prepared by hot-press sintering,α-Al2O3 effectively inhibites the grain growth of MgAlON through grain boundary pinning effect.As the sintering temperature increases,α-Al2O3 content in the composite ceramics decreases.At the same time,the optical transmittance of ceramics increases,while the mechanical properties and thermal conductivity decrease.The maximum in-line transmittance of sintered samples with 1 mm thickness from 1 500℃to 1 650℃is greater than 72.6%at a wavelength of 4 μm.Among them,1 600℃sintered sample shows the maximum in-line transmittance of 76.1%,elastic modulus of 321.69 Gpa,hardness of 15.93 Gpa,four-point fracture strength of 268.09 Mpa,fracture toughness of 2.41 Mpa·m1/2,and thermal conductivity of 13.98 W·m-1·K-1.

关键词

MgAlON-Al2O3/钉扎效应/显微结构/Van-de-Hulst理论/光学性能/机械性能

Key words

MgAlON-Al2O3/pinning effect/microstructure/Van-de-Hulst theory/optical property/mechanical property

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基金项目

国家重点研发计划(2023YFB3812000)

国家自然科学基金(52272072)

湖北隆中实验室自主创新研究项目(2022ZZ-13)

出版年

2024
硅酸盐通报
中国硅酸盐学会 中材人工晶体研究院

硅酸盐通报

CSTPCD北大核心
影响因子:0.698
ISSN:1001-1625
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