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低温环境下硅灰对掺无碱速凝剂水泥砂浆抗压强度和抗渗性的影响

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低温环境会影响隧道喷射混凝土早期性能的发展.本文研究了低温环境下硅灰对掺无碱速凝剂水泥砂浆流动性、抗压强度和抗渗性的影响,并采用XRD、TG-DTG和MIP分析了水化产物和孔结构的变化.结果表明:低温下硅灰显著提高了砂浆的1 d抗压强度,增幅超过300.0%;添加5%(质量分数)的硅灰能小幅增强28 d抗压强度,增幅达4.7%.此外,砂浆的抗渗性随着硅灰掺量的增加而提升,当添加的硅灰超过10%时,砂浆抗渗能力明显增强.在低温环境下,硅灰可以发挥火山灰效应和微填充效应,使多害孔朝少害孔方向转化,细化孔结构,使浆体结构更加密实,从而提高砂浆的抗压强度和抗渗性.
Influence of Silica Fume on Compressive Strength and Impermeability of Cement Mortar with Alkali-Free Accelerator at Low Temperatures
Low temperature environment affects the development of early performance of tunnel shotcrete.This study investigated the effects of silica fume on the fluidity,compressive strength,and impermeability of alkali-free accelerator-modified cement mortars at low temperatures.XRD,TG-DTG and MIP were used to analyze the changes in hydration products and pore structure.The results show that using silica fume significantly improves the 1 d compressive strength of mortar at low temperatures with an increase of over 300.0%.At 28 d,incorporating 5%(mass fraction)silica fume also increased the compressive strength by 4.7%.Moreover,the impermeability of mortar increases with the increase of the silica fume content.Especially,the impermeability is remarkably improved when the content of silica fume exceeded 10%.Silica fume modification can exert the pozzolanic effect and micro-filling effect at low temperatures,which transformes more-harmful pores towards less-harmful ones,refining the pore structure and making the paste structure denser,thereby improving the compressive strength and impermeability of mortars.

low temperaturesilica fumealkali-free acceleratorcompressive strengthimpermeabilitymicrostructure

刘亚炜、胡阳、罗琦、鲁刘磊、裴大田、李斌斌、马俊、汪峻峰

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深圳大学土木与交通工程学院,深圳 518060

建华建材(中国)有限公司,镇江 212000

中国建筑第八工程局有限公司,深圳 518000

佛山格耐特新型建筑材料科技有限公司,佛山 528000

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低温 硅灰 无碱速凝剂 抗压强度 抗渗性 微观结构

2024

硅酸盐通报
中国硅酸盐学会 中材人工晶体研究院

硅酸盐通报

CSTPCD北大核心
影响因子:0.698
ISSN:1001-1625
年,卷(期):2024.43(9)