首页|碱激发螯合生活垃圾焚烧飞灰力学性能和毒性浸出特性

碱激发螯合生活垃圾焚烧飞灰力学性能和毒性浸出特性

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生活垃圾焚烧飞灰螯合固化后,仍存在一定环境隐患,填埋会占用大量土地,将其再利用可以减缓填埋场的压力.本文采用碱激发技术制备螯合飞灰-矿粉基碱激发胶凝材料,除探讨碱激发螯合飞灰的可行性以外,还研究了氧化钙掺量对胶凝材料性能的影响.结果表明,在氧化钙掺量为4%(质量分数)时,固化体的抗压强度最高,而当氧化钙掺量超过4%时,固化体的抗压强度则会缓慢减小.氧化钙的加入促进了 C-S-H凝胶水化产物的形成,显著提高了材料的抗压强度.同时,通过浸出试验发现掺入氧化钙的固化体的重金属浸出浓度低于未掺氧化钙的固化体,并且满足规定《生活垃圾填埋场污染控制标准》(GB 16889-2008)限制值.
Mechanical Properties and Toxic Leaching Characteristics of Alkali-Activated Chelated Municipal Solid Waste Incinerator Fly Ash
After the chelation and solidification of municipal solid waste incineration fly ash,there are still certain environmental hazards.Landfilling will occupy a large amount of land,and reusing can alleviate the pressure on landfill site.This article used alkali activation technology to prepare chelated fly ash mineral powder based alkali-activated cementitious material.In addition to exploring the feasibility of alkali-activated chelated fly ash,the influence of calcium oxide content on improving the performance of cementitious material was also explored.The results show that the compressive strength of solidified body is highest when calcium oxide content is 4%(mass fraction),while the compressive strength of solidified body slowly decreases when calcium oxide content exceedes 4%.The addition of calcium oxide promotes the formation of hydration products of C-S-H gel and significantly improves the compressive strength of material.Meanwhile,through leaching tests,it is found that the heavy metal leaching concentration of solidified body doped with calcium oxide is lower than that of solidified body without calcium oxide,and meets the limit values specified in"Standard for pollution control on the landfill site of municipal solid waste"(GB 16889-2008).

municipal solid waste incinerator fly ashchelated fly ashalkali-activated cementitious materialcompressive strengthtoxicity leaching

卢诗琳、丁秀明、罗琦、叶伟开、董发鑫、吴培喜、马俊、汪峻峰

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深圳大学土木与交通工程学院,深圳 518061

防灾科技学院土木工程学院,廊坊 065201

中国建筑第八工程局有限公司,深圳 518000

生活垃圾焚烧飞灰 螯合飞灰 碱激发胶凝材料 抗压强度 毒性浸出

海南省重点研发项目

ZDYF2022SHFZ322

2024

硅酸盐通报
中国硅酸盐学会 中材人工晶体研究院

硅酸盐通报

CSTPCD北大核心
影响因子:0.698
ISSN:1001-1625
年,卷(期):2024.43(10)