硅酸盐通报2024,Vol.43Issue(12) :4501-4511.

费托合成废渣制备P型分子筛及其应用研究

Preparation of P-Type Molecular Sieves from Fischer-Tropsch Synthesis Waste Slag and Its Applications

李乔乔 刘红缨 张秋雯 王绿茵 谭祈祥
硅酸盐通报2024,Vol.43Issue(12) :4501-4511.

费托合成废渣制备P型分子筛及其应用研究

Preparation of P-Type Molecular Sieves from Fischer-Tropsch Synthesis Waste Slag and Its Applications

李乔乔 1刘红缨 1张秋雯 1王绿茵 1谭祈祥1
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作者信息

  • 1. 中国矿业大学(北京)化学与环境工程学院,北京 100083
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摘要

工业费托合成工艺路线所产生的废渣含有大量硅和铝元素,为了实现高效资源化利用,本文以除蜡后的费托合成废渣为原料,通过碱熔融-水热法制备P型分子筛,系统考察了硅铝比、碱硅比、晶化温度及晶化时间对P型分子筛制备的影响,采用XRD、FT-IR、SEM等表征手段对分子筛进行晶型、形貌和结构分析,并对P型分子筛吸附Pb2+性能进行了研究.结果表明:废渣在 n(SiO2)/n(Al2O3)=6.5,n(Na2O)/n(SiO2)=1.8、T=90 ℃和t=24 h条件下合成的P型分子筛,形貌轮廓清晰、形状规则,无杂质晶相,相对结晶度最高,达86.39%,且比表面积最大,达99.8 m2/g.费托合成废渣基P型分子筛对Pb2+的最大平衡吸附容量达322.85 mg,对吸附过程进行吸附动力学分析发现其符合准二级动力学模型,吸附平衡量为319.47 mg/g.

Abstract

In order to realize the efficient resource utilization of industrial Fischer-Tropsch synthesis process,P-type molecular sieves were prepared from Fischer-Tropsch synthesis residue with a lot of silicon and aluminum after dewaxing by alkali-fusion-hydrothermal method.The effects of Si/Al ratio,alkali/Si ratio,crystallization temperature and crystallization time on the preparation of P-type molecular sieves were systematically investigated.XRD,FT-IR,SEM and other characterization means were used to analyze the crystalline shape,morphology and structure of the molecular sieves,and the adsorption properties of P-type molecular sieves with Pb2+were investigated.The results show that the P-type molecular sieves synthesized from waste slag under the conditions of n(SiO2)/n(Al2O3)=6.5,n(Na2O)/n(SiO2)=1.8,T=90cC,and t=24 h have a clear and regular morphology profile,no impurity crystalline phases,the highest degree of crystallinity,which is 86.39%,and the largest specific surface area,which is 99.8 m2/g.The maximum equilibrium adsorption capacity of Pb2+in the Fischer-Tropsch synthesis waste slag-based P-type molecular sieves reaches 322.85 mg.The adsorption process is analyzed for adsorption kinetics and it is found that the process conformed to a quasi-secondary kinetic model with an adsorption equilibrium of 319.47 mg/g.

关键词

费托合成废渣/P型分子筛/碱熔融-水热法/Pb2+吸附/动力学模型/吸附容量

Key words

Fischer-Tropsch synthesis waste slag/P-type molecular sieve/alkali-fusion-hydrothermal method/Pb2+adsorption/kinetic model/adsorption capacity

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出版年

2024
硅酸盐通报
中国硅酸盐学会 中材人工晶体研究院

硅酸盐通报

CSTPCD北大核心
影响因子:0.698
ISSN:1001-1625
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