硅酸盐通报2024,Vol.43Issue(12) :4571-4577,4587.

低密度高强度陶粒支撑剂的制备及性能研究

Preparation and Properties of Low-Density and High Strength Ceramic Proppants

丰铭 吉国荣 高云峰 牟维鹏 朱保顺 田玉明 白频波
硅酸盐通报2024,Vol.43Issue(12) :4571-4577,4587.

低密度高强度陶粒支撑剂的制备及性能研究

Preparation and Properties of Low-Density and High Strength Ceramic Proppants

丰铭 1吉国荣 1高云峰 1牟维鹏 1朱保顺 1田玉明 2白频波3
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作者信息

  • 1. 山西科技学院材料科学与工程学院,晋城 048012
  • 2. 山西科技学院材料科学与工程学院,晋城 048012;太原科技大学材料科学与工程学院,太原 030024
  • 3. 阳泉市长青石油压裂支撑剂有限公司,阳泉 045200
  • 折叠

摘要

以二级铝矾土(Al2O3质量分数70.3%)和粉煤灰为原料,以不同含量的白云石为添加剂,在1 350℃下烧结制备了低密度高强度的陶粒支撑剂,有效利用了固废粉煤灰,并探究了白云石对陶粒支撑剂晶粒发育的作用及对性能的影响.通过XRD、SEM及物理性能测试仪等表征手段,研究了白云石含量对铝矾土-粉煤灰系陶粒支撑剂微观结构及物理性能的影响.结果表明,适量白云石的添加可明显促进棒状莫来石晶体的生长发育,降低陶粒支撑剂的破碎率.此外,基体内闭气孔的产生可降低陶粒支撑剂的体积密度和视密度.当白云石的添加量为6%(质量分数)时,所制备的陶粒支撑剂性能最佳,体积密度为1.45 g/cm3,视密度为2.60 g/cm3,35 MPa下的破碎率为6.5%.

Abstract

A low-density and high strength ceramic proppant was prepared using secondary bauxite(Al2 O3 mass fraction 70.3%)and fly ash as raw materials,with different content of dolomite as additive,at a sintering temperature of 1 350 ℃.The solid waste fly ash was effectively utilized,and the influence of dolomite on the grain development and properties of ceramic proppants was investigated.The influence of dolomite content on the microstructure and physical properties of bauxite-fly ash based ceramic proppants was studied through characterization methods such as XRD,SEM,and physical performance testers.The results show that the addition of appropriate content of dolomite can significantly promote the growth and development of rod-shaped mullite,and reduce the crushing rate of ceramic proppants.In addition,the formation of closed pores within the matrix can reduce the bulk density and apparent density of ceramic proppants.When the addition content of dolomite is 6%(mass fraction),the prepared ceramic proppants has the best performance,with a bulk density of 1.45 g/cm3,an apparent density of 2.60 g/cm3,and a crushing rate of 6.5%at 35 MPa.

关键词

铝矾土/粉煤灰/陶粒支撑剂/白云石/低密度/破碎率

Key words

bauxite/fly ash/ceramic proppant/dolomite/low-density/crushing rate

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出版年

2024
硅酸盐通报
中国硅酸盐学会 中材人工晶体研究院

硅酸盐通报

CSTPCD北大核心
影响因子:0.698
ISSN:1001-1625
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