硅酸盐通报2024,Vol.43Issue(12) :4639-4648.

可见光光催化/抗菌功能Ag/CuO/TiO2/天然沸石复合材料的制备及性能

Preparation and Properties of Ag/CuO/TiO2/Natural Zeolite Based Composites with Visible Light Photocatalytic/Antibacterial Properties

于倩茹 王李鹏 都扶岭 梁鑫超 刘思琪 王程
硅酸盐通报2024,Vol.43Issue(12) :4639-4648.

可见光光催化/抗菌功能Ag/CuO/TiO2/天然沸石复合材料的制备及性能

Preparation and Properties of Ag/CuO/TiO2/Natural Zeolite Based Composites with Visible Light Photocatalytic/Antibacterial Properties

于倩茹 1王李鹏 1都扶岭 1梁鑫超 1刘思琪 1王程2
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作者信息

  • 1. 陕西科技大学材料科学与工程学院,西安 710021
  • 2. 陕西科技大学材料科学与工程学院,西安 710021;陕西省无机材料绿色制备与功能化重点实验室,西安 710021
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摘要

采用浸渍-煅烧法在酸处理沸石表面固载CuO/TiO2颗粒,再采用离子交换/光还原法在CuO/TiO2/天然沸石表面固载Ag纳米颗粒,制备得到Ag/CuO/TiO2/天然沸石复合材料;进一步将该复合材料与白水泥和乳胶粉混合得到沸石基环保涂料.采用XRD、FT-IR、SEM-EDX、N2吸附-脱附、UV-Vis DRS、PL等测试对材料的组成和结构进行表征,采用甲基橙和大肠杆菌分别评价材料的光催化和抗菌性能.结果表明,制备的Ag/CuO/TiO2/天然沸石复合材料的比表面积达146 m2·g-1,光响应范围可拓展至506 nm,具有较低的电子-空穴对复合概率.材料在氙灯照射240 min后,对甲基橙的去除率可达93.2%,在光照5 min后的抗菌率近100%.

Abstract

The Ag/CuO/TiO2/natural zeolite composites were prepared by impregnation-calcination method to immobilize CuO/TiO2 particles on the surface of natural zeolite after acid treatment,and then Ag nanoparticles were immobilized on the surface of CuO/TiO2/natural zeolite by ion exchange/photoreduction method.The composites were further mixed with white cement and latex powder to obtain a zeolite based environmental protection coating.The composition and structure of materials were characterized by XRD,FT-IR,SEM-EDX,N2 adsorption-desorption,UV-Vis DRS,PL and other tests.The photocatalytic and antibacterial properties of materials were evaluated by methyl orange and escherichia coli,respectively.The results show that the specific surface area of prepared Ag/CuO/TiO2/natural zeolite composites is 146 m2·g-1,and the light response range can be extended to 506 nm,which has a low electron-hole pair recombination probability.After 240 min of xenon lamp irradiation,the removal rate of methyl orange is 93.2%,and the antibacterial rate is nearly 100%after 5 min of irradiation.

关键词

Ag/CuO/TiO2/天然沸石/环保涂料/吸附/可见光光催化/抗菌/酸处理

Key words

Ag/CuO/TiO2/natural zeolite/environmental protection coating/adsorption/visible light photocatalysis/antibacterial/acid treatment

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出版年

2024
硅酸盐通报
中国硅酸盐学会 中材人工晶体研究院

硅酸盐通报

CSTPCD北大核心
影响因子:0.698
ISSN:1001-1625
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