首页|提钒尾渣煤基回转窑法钙化还原脱钠研究

提钒尾渣煤基回转窑法钙化还原脱钠研究

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针对提钒尾渣中钠含量高,导致难以返回烧结-高炉流程进行回收利用的问题,提出基于煤基回转窑还原的提钒尾渣钙化还原脱钠技术路线,并在Ø1 m×10m回转窑中试线进行半工业试验,主要研究了高温段还原温度、白灰配比、入窑吨球焦粉配比、高温还原时间对提钒尾渣脱钠的影响规律,同时对脱钠后球团性能和回转窑结窑情况进行分析.结果表明,在高温段温度为1 100~1 160℃,高温段时间为1.8~2 h,入窑吨球焦粉配比为800~1 000 kg,白灰配比为32.5%~41%的条件下,提钒尾渣脱钠率可达到80%以上,吨球焦粉实际消耗量为359 kg.窑内结块物主要由提钒尾渣球团粉末和焦粉灰分粉末组成,结块物呈疏松多孔状,由细颗粒相互粘结构成,窑转动过程会自动掉落,无明显结窑现象.
Study on calcification reduction sodium removal of vanadium extraction tailings by coal-based rotary kiln method
In view of the high sodium content in vanadium extraction tailings,which leads to the diffi-culty of returning to the sintering-blast furnace process for recycling,herein we proposed a calcification reduction sodium removal technology route for vanadium extraction tailings based on coal-based rotary kiln reduction,and conducted a semi-industrial test on a Ø1 m×10 m rotary kiln pilot line.The influ-ence of reduction time in the high temperature section,white ash ratio,into the kiln ton-ball coke ratio and high temperature reduction time on vanadium extraction tailings sodium removal was mainly stud-ied.At the same time,the performance of pellets after desalination and the situation of kiln formation in the rotary kiln were analyzed.Under the conditions of high temperature section temperature of 1 100~1 160 ℃,high temperature section time of 1.8~2 h,into the kiln ton-ball coke ratio of 800~1 000 kg,white ash ratio of 32.5%~41%,the sodium removal rate of vanadium extraction tailings can reach more than 80%,and the coke consumption is 359 kg.The agglomeration in the kiln is mainly composed of vanadium extraction tailings pellet powder and coke ash powder.The agglomeration is loose and por-ous,consisting of fine particles which are sticky to each other.The agglomeration will fall off automat-ically during the kiln rotation process,without obvious kiln formation phenomenon.

vanadium extraction tailingcalcification reductionsodium removalrotary kiln reduction

王兆才、郑富强、刘臣、胡兵、师本敬

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中冶长天国际工程有限责任公司,湖南长沙 410007

国家烧结球团装备系统工程技术研究中心,湖南长沙 410205

提钒尾渣 钙化还原 脱钠 回转窑还原

湖南省重点研发计划

2023SK2079

2024

钢铁钒钛
攀钢集团攀枝花钢铁研究院有限公司

钢铁钒钛

CSTPCD北大核心
影响因子:0.395
ISSN:1004-7638
年,卷(期):2024.45(1)
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