首页|钛白粉表面结构与水分散性间的构效关系研究

钛白粉表面结构与水分散性间的构效关系研究

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钛白粉初品的水润湿分散性对无机包膜以及应用性能至关重要.以锌盐和铝盐处理的钛白初品为研究对象,研究钛白初品表面结构与水润湿分散性之间的关系.结果表明,采用锌盐处理剂获得的钛白初品球形度好、粒度小,铝盐处理的钛白初品呈长条状,具有更丰富的表面羟基、更高的表面能以及更厚的双电层结构.此外,在分散剂加量为0.2%,TiO2浓度为700 g/L时,锌盐初品浆料黏度946 mPa·s,Zeta电位为-23.3 mV,铝盐初品浆料黏度512 mPa·s,Zeta电位为-31.2 mV.表明铝盐初品的浆料黏度更低,分散性更好,水润湿分散性更优异.对不同盐处理钛白初品表面结构进行分析研究,建立表面结构与水分散性之间的构效关系,为开发高端钛白粉提供借鉴和思路.
Structure-property relationship between surface structure and water dispersity of titanium dioxide
The wettability and dispersion of titanium dioxide in water is very important for the inorgan-ic coating and application performance.In this study,the relationship between the surface structure and the water wettability and dispersion of titanium dioxide treated with zinc and aluminum salts was stud-ied.The results show that the initial titanium dioxide treated with zinc salt has good sphericity and small particle size,and the initial titanium dioxide treated with aluminum salt has a long strip shape,with rich-er surface hydroxyl,higher surface energy and thicker electric double layer structure.In addition,when the dosage of dispersant was 0.2%and the concentration of TiO2 was 700 g/L,the viscosity of the ini-tial zinc salt slurry was 946 mPa·s,and the zeta potential was-23.3 mV.The viscosity of the initial alu-minum salt slurry was 512 mPa·s,and the zeta potential was-31.2 mV.The results show that the slurry viscosity of the aluminum salt is lower,the dispersion is better,and the water wetting dispersion is bet-ter.The surface structure of titanium dioxide treated with different salts was analyzed,and the structure-activity relationship between surface structure and water dispersion was established,which provided ref-erence and ideas for the development of high-end titanium dioxide.

titanium dioxidesalt treatment agentsurface energyviscositydisperse

全远霞、向泉锦、全学军、柯良辉、李礼

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重庆理工大学化学化工学院,重庆 400054

攀钢集团钒钛资源股份有限公司,四川攀枝花 617000

二氧化钛 盐处理剂 表面能 黏度 分散性

重庆理工大学科研项目重庆市教委科学技术研究计划

0115220003KJQN20221118

2024

钢铁钒钛
攀钢集团攀枝花钢铁研究院有限公司

钢铁钒钛

CSTPCD北大核心
影响因子:0.395
ISSN:1004-7638
年,卷(期):2024.45(2)