首页|镁对21-4N气阀钢中碳化物的影响

镁对21-4N气阀钢中碳化物的影响

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为了探究不同镁含量对21-4N气阀钢中液析碳化物的影响规律,采用实验室高温电阻炉冶炼了不同镁添加量的21-4N气阀钢,借助蔡司金相显微镜、扫描电子显微镜、电解腐蚀等方法开展研究.结果表明,随21-4N钢中Mg含量的增加,碳化物平均最大尺寸及面积占比均先减小后增大.添加微量的镁有助于改善钢中富Cr型液析碳化物的尺寸和分布,镁的质量分数为1.6×10-5时,液析碳化物平均最大尺寸为60.55 μm,面积占比10.43%,在钢中多呈颗粒状分布,连续性被破坏,其原因是镁元素在晶界处的偏聚,能够抑制C、Cr等合金元素的扩散,阻断碳化物连续生长,从而达到细化碳化物尺寸的效果.
Effect of Mg on carbides in 21-4N valve steel
In order to explore the influence of different magnesium content on primary carbides in 21-4N valve steel,21-4N valve steel with different magnesium content was smelted in a laboratory high temperature resistance furnace,and the research was carried out by use of Zeiss metallographic micro-scope,scanning electron microscope and electrolytic corrosion.The results show that with the increase of Mg content in 21-4N steel,both the average maximum size and area ratio of carbides firstly decrease and then increase.The addition of trace magnesium is helpful to improve the size and distribution of Cr-rich precipitated carbides in steel.When the mass fraction of magnesium is 1.6x10-5,the average max-imum size of precipitated carbides is 60.55 μm and its area ratio is 10.43%,and most of them are granu-lar in steel,and the continuity is destroyed.The reason is that the segregation of magnesium at the grain boundary can inhibit the diffusion of alloy elements such as C and Cr,and then block the continuous growth of carbide,thus achieving the effect of refining the carbide size.

21-4N valve steelMg modificationprimary carbide

季灯平、朱浩然、刘贝贝、孙晗、徐翔宇、付建勋

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上海大学材料科学与工程学院,先进凝固技术中心,省部共建高品质特殊钢冶金与制备国家重点实验室,上海 200444

浙江青山钢铁有限公司,浙江丽水 325000

21-4N气阀钢 镁改质 液析碳化物

国家自然科学基金资助项目国家自然科学基金资助项目

5187419552074179

2024

钢铁钒钛
攀钢集团攀枝花钢铁研究院有限公司

钢铁钒钛

CSTPCD北大核心
影响因子:0.395
ISSN:1004-7638
年,卷(期):2024.45(3)
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