首页|V含量对激光熔覆铁铬合金涂层组织结构及性能的影响

V含量对激光熔覆铁铬合金涂层组织结构及性能的影响

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采用激光熔覆技术制备了不同V含量的铁铬合金涂层,结合金相观察、SEM&EDS、X-射线衍射等分析方法研究了V含量变化时激光熔覆铁铬合金涂层的显微组织与性能的变化规律.结果表明,V含量较低时铁铬合金涂层以树枝晶生长模式为主,涂层界面的树枝晶生长过程中Cr元素来不及完全固溶到基体中,引起基体衍射峰向高角度处偏移.增加V含量能够促进树枝晶向胞状晶转变,有效改善了Cr元素在基体中不能完全固溶的现象.VC的形成促进了凝固过程中γ-Fe向马氏体的转变,涂层硬度提升,但当V含量增加到 2%时,原料中高熔点钒铁含量增加,导致涂层中气孔缺陷增加,引起涂层耐磨性能降低.当V含量为1%时涂层性能最佳.
Effect of V content on microstructure and properties of laser cladding Fe-Cr alloy coatings
Iron-chromium alloy coatings with varying V content were fabricated using laser cladding.The microstructural and performance variations of the laser-cladded iron-chromium alloy coatings with different V contents were investigated using metallographic observation,SEM&EDS,and X-ray dif-fraction analysis.The results indicate that at lower V content,the iron-chromium alloy coating predom-inantly exhibits a dendritic growth mode.At the coating interface,the dendritic grew rapidly,Cr ele-ments do not have sufficient time to completely dissolve into the matrix,causing the matrix diffraction peaks to shift to higher angles.Increasing V content promotes the transition from dendritic to cellular growth,effectively improving the incomplete dissolution of Cr elements in the matrix and leading to a more uniform coating structure.The formation of VC promotes the transformation of γ-Fe to martensite during solidification,and the hardness of the coating increases.However,when the V content increases to 2%,the ferrovanadium content with a higher melting point increases,resulting in an increase in pore defects,which makes the wear resistance of the coating decrease.When the V content in the coating is 1%,the hardness and wear resistance are the best.

laser claddingVCiron-chromium alloy coatingmicrostructureperformance

张雪峰、卿光洋、周浩然、翁刘、陈敏、赵海泉、吴博涛、张鑫

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钒钛资源综合利用四川省重点实验室,四川 攀枝花 617000

国家钒钛检测重点实验室,四川 攀枝花 617000

四川钒钛产业技术研究院,四川 攀枝花 617000

四川国鑫机械制造有限公司,四川 攀枝花 617000

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激光熔覆 VC 铁铬合金涂层 显微组织 性能

2024

钢铁钒钛
攀钢集团攀枝花钢铁研究院有限公司

钢铁钒钛

CSTPCD北大核心
影响因子:0.395
ISSN:1004-7638
年,卷(期):2024.45(6)