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未燃煤粉及其还原产物在高钛型高炉渣中的行为研究

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采用旋转柱体法对配加未燃煤粉的高钛型高炉渣的黏度进行了测量,结合试验样品的宏观形貌和不同部位微观结构的表征,对未燃煤粉及其还原产物在高钛型高炉渣中的行为进行了分析.结果表明,未燃煤粉不可避免地会与渣中TiO2 反应,残余的未燃煤粉及其还原产物,如Ti(C,N)或TiCxOy等高熔点物相不均匀分布于渣中.随着初始未燃煤粉含量从 0增加至 5.51%,渣中TiC和TiN含量之和从 0.456%升高至 2.515%,反应生成的高熔点物质向下沉降聚集,残余的未燃煤粉则向上运动,与上部炉渣中的TiO2 继续反应生成高熔点物质或形成泡沫渣,并导致炉渣黏度显著升高,波动显著加剧,炉渣中部则几乎没有残余未燃煤粉和高熔点还原产物.
Study on the behavior of unburnt pulverized coal and reduction productions of TiO2 in high-titanium blast furnace slag
In this study,the viscosity of high-titanium blast furnace slags uniformly mixed with unburnt pulverized coal(UPC)was measured by using the method of rotating cylinder firstly.Then the distribu-tion and behavior of the residual UPC and the reduction products were analyzed according to the macro morphology of these samples and their microscopic morphology of different parts.It was found that TiO2 would inevitably be reduced by UPC,the high melting point reduction products such as Ti(C,N),TiCxOy and unburnt UPC distributed nonuniformly in the slag.As the initial UPC content increased from 0%to 5.51%,the total content of TiC and TiN increased from 0.456%to 2.515%.The high melt-ing point reduction products deposited downwards and aggregated,while the unburnt UPC floated up-wards and continued to react with TiO2 to form foam slag,resulting in a significant increase in both vis-cosity and its fluctuation.However,there were negligible residual unburnt UPC and high melting point reduction products in the middle of the slag.

high-titanium blast furnace slagunburnt pulverized coalreduction behaviorviscosityti-tanium carbonitride

谢洪恩、郑魁、胡鹏、唐文博、令新科

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攀钢集团研究院有限公司,钒钛资源综合利用国家重点实验室,四川 攀枝花 617000

高钛型高炉渣 未燃煤粉 还原行为 黏度 碳氮化钛

2024

钢铁钒钛
攀钢集团攀枝花钢铁研究院有限公司

钢铁钒钛

CSTPCD北大核心
影响因子:0.395
ISSN:1004-7638
年,卷(期):2024.45(6)