首页|老化SBS改性沥青的结构修复与性能评价

老化SBS改性沥青的结构修复与性能评价

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为恢复老化SBS改性沥青良好的使用性能,该研究使用菜籽油生物沥青(COA)与聚亚甲基多苯基异氰酸酯(PAPI)分别进行沥青组分调节,并修复SBS分子结构.通过对比不同再生组分对短期老化SBS改性沥青物理流变性能及分子量分布的影响,验证上述的双重再生机理.同时,根据未老化基质沥青与SBS改性沥青流变性能在双重再生剂作用下的变化规律,排除再生剂自身对相位角平台区的影响.在综合考虑双重再生SBS改性沥青的物理与流变性能情况下,分别确定COA与PAPI的最佳掺量.试验结果表明:双重再生剂不仅可以调节沥青组分,还能修复SBS分子结构,进而恢复老化SBS改性沥青物理与流变性能.双重再生剂的最佳配比为12%COA+1.25%PAPI;荧光显微镜测试结果进一步验证了PAPI具有重建SBS网络结构的作用.
Structural Repair and Performance Evaluation of Aged SBS Modified Asphalt
To rejuvenate the excellent performance of aged styrene-butadiene-styrene(SBS)modified asphalt,colza oil bio-asphalt(COA)and polymethylene polyphenyl isocyanate(PAPI)were used in this study for adjusting the asphalt components and repairing SBS molecular structure,respectively.The above-mentioned dual regeneration mechanism was verified by comparing the effects of different rejuvenation components on the physical and rheological properties,as well as the molecular weight distribution of short-term aged SBS modified asphalt.Moreover,according to the change law of rheological properties of unaged base asphalt and SBS modified asphalt under the effect of dual regeneration agent,the influence of the regeneration agent on the phase angle platform area was excluded.Under the comprehensive consideration of the physical and rheological properties of dual regeneration SBS modified asphalt,the optimal contents of COA and PAPI were determined.The experimental results indicate that the double regeneration agent can not only regulate the asphalt components but also connect the SBS molecular structure,restoring the physical and rheological properties of aged SBS modified asphalt.The optimal ratio of the dual regeneration agent is determined to be 12% COA and 1.25% PAPI.In addition,the fluorescence microscopy test results further verify that PAPI can rebuild the SBS network structure.

SBS modified asphaltasphalt component adjustmentco-polymer structure reconstructiondual regenerationphysical and rheological properties

徐光、李启石、旷华平、张恒龙、周睿博、陈艳梅

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湖南国信路面环保材料有限责任公司,湖南 株洲 412100

湖南大学 绿色先进土木工程材料及应用技术湖南省重点实验室,湖南 长沙 410082

湖南云中再生科技股份有限公司 湖南省建筑固废资源化利用工程技术研究中心,湖南 长沙 410205

SBS改性沥青 沥青组分调节 共聚结构重建 双重再生 物理流变性能

国家自然科学基金资助项目湖南省杰出青年科学基金资助项目

523784492024JJ2019

2024

中外公路
长沙理工大学

中外公路

CSTPCD
影响因子:0.626
ISSN:1671-2579
年,卷(期):2024.44(5)
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