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固定化锑氧化菌K.aerogenes HC10去除水中Sb(Ⅲ)的效果及机制

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针对水环境中Sb(Ⅲ)的毒性问题,采用包埋法制备了固定化锑氧化菌,研究其去除水中Sb(Ⅲ)的效果和机制.通过改变不同固定化锑氧化菌投加量、Sb(Ⅲ)初始浓度、初始pH探究不同因素对固定化锑氧化菌治理含锑废水的影响.结果表明:Sb(Ⅲ)的去除率随着固定化锑氧化菌投加量及初始pH的增大而增大,随着Sb(Ⅲ)初始浓度的增大而减小,在固定化锑氧化菌投加量为2%,Sb(Ⅲ)初始浓度为0.1 mmol/L、初始pH为8.5条件下,培养72 h,Sb(Ⅲ)去除率达到74.31%.通过扫描电子显微镜和傅里叶变换红外光谱对固定化锑氧化菌进行了表征,发现固定化锑氧化菌内部呈多孔三维网状结构,为锑氧化菌的生长繁殖提供营养和场所,而且对Sb(Ⅲ)有较好的吸附作用;官能团—OH、—C-O、—C=C对锑的结合起着主要作用.
Removal effect and mechanism of Sb(Ⅲ)from water by immobilized antimony oxidizing bacteria K.aerogenes HC10
In view of the toxicity of Sb(Ⅲ)in the aqueous environment,we prepared immobilized antimony oxidizing bacteria by embedding method,aiming to study the effect and mechanism of their removal of Sb(Ⅲ)in water.The effects of different factors on the treatment of antimony-containing wastewater by immobilized antimony oxidizing bacteria were investigated by changing the dosage amount,initial concentration of Sb(Ⅲ)and initial pH value of immobilized antimony oxidizing bacteria.The results showed that the removal rate of Sb(Ⅲ)increased with the increase of the amount and initial pH of the immobilized antimony oxidizing bacteria,and decreased with the increase of the initial concentration of Sb(m),and the removal rate of Sb(Ⅲ)reached 74.31%after 72 h of culture under the conditions of 2%of the immobilized antimony oxidizing bacteria,0.1 mmol/L of Sb(Ⅲ)and 8.5 of the initial pH.The immobilized antimony oxidizing bacteria were characterized by scanning electron microscopy and Fourier transform infrared spectroscopy,and it was found that the immobilized antimony oxidizing bacteria had a porous 3D network structure,which provided nutrients and places for the growth and reproduction of antimony oxidizing bacteria,and had a good adsorption effect on Sb.The functional groups—OH,—C—O,—C=C play a major role in the binding of antimony.

immobilized antimony oxidizing bacteriawater treatmentadsorption

祁曼、孙艺、卢定添、尚可、任义帅、零彩苑、黄何、张超兰

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广西大学资源环境与材料学院,广西南宁 530004

广西大学 生命科学与技术学院,广西 南宁 530004

广西大学广西高校环境保护重点实验室,广西南宁 530004

固定化锑氧化菌 水处理 吸附

国家自然科学基金项目广西自然科学基金项目广西大学大学生创新训练项目

422670012020GXNSFAA297035202110593096

2024

广西大学学报(自然科学版)
广西大学

广西大学学报(自然科学版)

CSTPCD北大核心
影响因子:0.767
ISSN:1001-7445
年,卷(期):2024.49(4)