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再生骨料生态混凝土的强度特性与降碱效果研究

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为了解决再生骨料生态混凝土过高的碱性制约其推广应用的问题,本文以工程渣土再生骨料为研究对象,通过L16(44)正交表设计生态混凝土配合比,研究了设计孔隙率、水胶比、粉煤灰掺量和硅灰掺量对生态混凝土的酸碱度、有效孔隙率、抗压强度、抗折强度和劈裂抗拉强度这5个测试指标的影响规律,结合Z值综合评价法筛选得到最优配合比,研究了喷涂硅烷浸渍剂和质量分数为2%的过磷酸钙溶液、掺入过磷酸钙或氯化铝对生态混凝土的降碱效果.结果表明:①再生骨料生态混凝土的最优配合比:设计孔隙率为24%,水胶比为0.34,粉煤灰掺量为30%,硅灰掺量为6%.②设计孔隙率对生态混凝土的酸碱度、有效孔隙率、抗压强度、抗折强度和劈裂抗拉强度的影响程度大于水胶比、粉煤灰掺量和硅灰掺量分别对这5个测试指标的影响程度,是这5个测试指标的主要影响因素.③喷涂1次硅烷浸渍剂可将生态混凝土的pH降至8.55,其降碱效果最好;其次是掺入6%氯化铝和6%过磷酸钙,生态混凝土 pH降至9.54和9.65;喷涂3次质量分数为2%的过磷酸钙溶液仅能将生态混凝土 pH降至10.26,其降碱效果较差.
Study on strength characteristics and alkali reduction effect of eco-concrete with recycled aggregates
To address the issue that the excessive alkalinity of recycled aggregate eco-concrete restricts its popularization and application,in this research,the recycled aggregate from construction spoil is taken as the research object,different eco-concrete mix ratios are designed by an L16(44)orthogonal table to explore the influence that design porosity,water-to-binder ratio,fly ash content,and silica fume content exert on test indexes of eco-concrete,including pH,effective porosity,compressive strength,flexural tensile strength,and splitting tensile strength.The optimal eco-concrete mix ratio is selected using the Z-score method to further study alkali reduction effects.Four methods are used for reducing alkalinity:spraying a silane impregnation,spraying a 2%mass fraction of calcium superphosphate solution,mixing calcium superphosphate,and mixing aluminum chloride.The results indicate that:①The recycled aggregate eco-concrete at the optimal mix ratio is made with a water-to-binder ratio of 0.34 which contains 30%fly ash and 6%silica fume.Meanwhile,the designed porosity of the eco-concrete is 24%.②The effect of design porosity on the pH,effective porosity,compressive strength,flexural tensile strength,and splitting tensile strength of eco-concrete is significantly greater than that of water-to-binder ratio,fly ash content,and silica fume content on the five test indexes.This makes design porosity the main factor affecting these five test indexes.③The most effective method for reducing alkalinity is by spraying silane impregnation once,and the pH can be reduced to 8.55.This is followed by adding 6%aluminum chloride and 6%calcium superphosphate,which reduce the pH of eco-concrete to 9.54 and 9.65,respectively.However,spraying a 2%mass fraction of calcium superphosphate solution three times can only reduce the pH of eco-concrete to 10.26,which is the worst method for reducing alkalinity.

construction spoilrecycled aggregateeco-concretestrength characteristicalkali reduction effect

廖丽萍、严裕佳、马少坤、庞兴志、陈润成

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广西大学土木建筑工程学院,广西南宁 530004

省部共建特色金属材料与组合结构全寿命安全国家重点实验室,广西南宁 530004

工程防灾与结构安全教育部重点实验室,广西南宁 530004

广西防灾减灾与工程安全重点实验室,广西南宁 530004

广西青辉环保技术有限责任公司,广西崇左 532100

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工程渣土 再生骨料 生态混凝土 强度特性 降碱效果

2024

广西大学学报(自然科学版)
广西大学

广西大学学报(自然科学版)

CSTPCD北大核心
影响因子:0.767
ISSN:1001-7445
年,卷(期):2024.49(6)