化工技术与开发2025,Vol.54Issue(1) :6-10,65.

β-FeOOH对氯化锂溶液的吸附除杂研究

Study on Impurities Removal of Lithium Chloride Solution Applied β-FeOOH as Adsorbent

李立平 邱焕彬 李煜乾 黄司平
化工技术与开发2025,Vol.54Issue(1) :6-10,65.

β-FeOOH对氯化锂溶液的吸附除杂研究

Study on Impurities Removal of Lithium Chloride Solution Applied β-FeOOH as Adsorbent

李立平 1邱焕彬 1李煜乾 1黄司平1
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作者信息

  • 1. 广东光华科技股份有限公司,广东汕头 515000
  • 折叠

摘要

以含氟和磷酸根的氯化锂溶液为研究对象,基于化学沉淀和静态吸附的对比结果,系统研究了在不同的条件下四方纤铁矿(β-FeOOH)对F-和PO43-的吸附效果.结果表明,β-FeOOH的吸附除杂效果显著优于铁盐化学沉淀.吸附剂用量、吸附温度和离子浓度的提高,均有利于对阴离子的吸附,弱酸性或中性条件有利于提高吸附性能.β-FeOOH对F-和PO43-的吸附容量分别为79.9mg·g-1和29.8mg·g-1,吸附机制主要是静电引力和化学吸附共同作用.

Abstract

Based on the lithium chloride solution containing fluorine and phosphate,as well as the comparative results between chemical precipitation and static adsorption,the effects of akaganeite(β-FeOOH)on the adsorption of F-and PO43-have been comprehensively investigated.The results show that the efficiency of impurity removal by β-FeOOH is superior to that of chemical precipitation.Increases in the amount of adsorbent,adsorption temperature,and ion concentration are conducive to the adsorption capacity of anions.In addition,β-FeOOH exhibits better adsorption performance under weakly acidic or neutral conditions.The adsorption capacities of F-and PO43-could reach 79.9mg/g and 29.8mg/g,respectively.The adsorption mechanism is predominantly a combination of electrostatic attraction and chemical adsorption.

关键词

氯化锂//磷酸根/四方纤铁矿/吸附

Key words

lithium chloride/fluorine/phosphate/akaganéite/adsorption

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出版年

2025
化工技术与开发
广西化工研究院

化工技术与开发

影响因子:0.301
ISSN:1671-9905
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