首页|PEO基固态电解质在锂金属电池的研究进展

PEO基固态电解质在锂金属电池的研究进展

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聚合物固态电解质因优异的可加工性、柔韧性、界面相容性以及充放电过程中的尺寸稳定性等优点而备受关注.但商业化的聚氧化乙烯(PEO)基聚合物电解质存在材料的结晶度高、电化学稳定性差等缺点,导致了电池的离子电导率低、循环性能不稳定、使用电压窗口窄等问题,严重限制了固态电池的推广应用.本文聚焦基于PEO材料的复合固态电解质的开发与应用,详细探讨了如何通过材料共混、掺杂改性和界面优化等措施来提高电解质的综合性能,以满足高安全性、高能量密度和长循环寿命的固态电池的需求,并对固态电解质未来的研究进行了展望.
Research Progress of PEO-based Solid-state Electrolytes in Lithium Metal Batteries
Polymer solid electrolytes have attracted much attention due to their excellent processability,flexibility,good interfacial compatibility,dimensional stability during charging and discharging.However,commercial polyethylene oxide(PEO)-based polymer electrolytes face challenges such as high material crystallinity and poor electrochemical stability,which lead to low ionic conductivity,unstable cycling performance,and a narrow voltage window for batteries,limiting the popularization and application of solid-state batteries.This review focus on the development and application of composite solid-state electrolytes made from PEO materials and discuss in detail how to improve the comprehensive performance of these electrolytes through material blending,doping modification,and interface optimization to meet the needs of solid-state batteries with high safety,high energy density,and long cycle life.Finally,the future research on solid-state electrolytes has look forward.

polymer solid electrolytePEO blending systemmaterial modificationinterface modifications

赵意、涂桦、张译文、沈平、谭文杰

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温州大学化学与材料工程学院,浙江温州 325000

聚合物固态电解质 PEO共混体系 材料改性 界面改性

2025

化工技术与开发
广西化工研究院

化工技术与开发

影响因子:0.301
ISSN:1671-9905
年,卷(期):2025.54(1)