首页|用废弃混凝土处理重金属污水

用废弃混凝土处理重金属污水

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本文建立了从废弃混凝土中分离水化硅酸钙(C-S-H)凝胶的新方法,利用C-S-H凝胶的大比表面积和高孔隙率来治理重金属污水.考察了在C-S-H凝胶吸附重金属的过程中,反应温度、反应时间、搅拌强度等参数对重金属去除效果的影响.结果表明,C-S-H凝胶去除工业废水中重金属元素的最佳条件为:反应温度60℃,反应时间30min,搅拌强度300r·min-1.在此条件下,C-S-H凝胶对重金属元素Cd、Cr、Cu、Hg、Ni、Pb的吸附容量,分别为20.0、22.5、15.0、20.0、17.5、12.5mg·g-1,在最佳反应条件下,所有重金属元素的去除率均大于98%.本方法为巨量废弃混凝土的大规模资源化再利用,实现工业废水中重金属元素的无害化处理开辟了新思路,达到了以废治废的目的.
Treatment of Heavy Metal Waste water with Waste Concrete
A new method of separating calcium silicate hydrate(C-S-H)gel from waste concrete was established.The large specific surface area and high porosity of C-S-H gel were used to treat heavy metal wastewater.The effects of reaction temperature,reaction time,stirring intensity and other parameters on the removal of heavy metals from industrial wastewater were investigated in the process of adsorption of heavy metals by C-S-H gel.The results showed that the optimal conditions for the removal of heavy metals from industrial wastewater by C-S-H gel were:reaction temperature 60℃,reaction time 30min,stirring intensity 300r/min.The adsorption capacity of C-S-H gel for heavy metals Cd,Cr,Cu,Hg,Ni,and Pb was 20.0,22.5,15.0,20.0,17.5,12.5mg/g,respectively.Under the optimal reaction conditions,the removal rate of all heavy metals was more than 98%.The method has opened up a new path for the large-scale resource utilization of massive waste concrete and the harmless treatment of heavy metal elements in industrial wastewater,achieving the goal of using waste to treat waste.

waste concretevindustrial wastewatercementitious materialscontrolheavy metal

刘宏伟、郑翔、侯伟、颜娇娇、唐鑫、杨梦成

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湖南工学院材料科学与工程学院,湖南衡阳 421002

衡阳市华江商砼有限公司,湖南衡阳 421008

废弃混凝土 工业废水 胶凝材料 治理 重金属

2025

化工技术与开发
广西化工研究院

化工技术与开发

影响因子:0.301
ISSN:1671-9905
年,卷(期):2025.54(1)