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离子型稀土矿山氨氮废水生物脱氮技术研究进展

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南方离子型稀土矿通常采用硫酸铵作浸矿剂进行提取开采,矿山开采后的很长一段时期都将产生大量的矿山地表氨氮废水,该废水的主要水质特征为有机碳源极缺、NH4+-N和NO3--N共存,废水脱氮成本高昂。以我国离子型稀土资源开采量最大的赣州市稀土矿区为例,分析了离子型稀土矿山氨氮废水的水量水质特征;比较了现有的离子型稀土矿山废水处理工程实践的工艺技术特点,并进行了理论成本分析;在分析常规厌氧氨氧化等新型生物脱氮技术在稀土矿山氨氮废水处理中的优势与不足的基础上,围绕水质特征与降低成本目标,提出了短程反硝化-短程硝化-厌氧氨氧化耦合工艺为离子型稀土矿山氨氮废水脱氮最优工艺。
Process on biological nitrogen removal technology of ammonia-nitrogen wastewater from ion-type rare earth mines
Ammonium sulfate is a commonly used leaching agent in the mining process of southern ion-type rare earth mines,which causes large quantities of mine ammonia-nitrogen wastewater under the leaching action of rain-water even after stopping mining for a long time.The typical characteristics of ion-type rare earth mine ammonia-nitrogen wastewater are extreme low C/N,coexistence of ammonia and nitrate,which increased the cost and diffi-culty of nitrogen removal.Taking Ganzhou rare earth mining area,which had the largest amount of ionic rare earth resources in China,as an example,the water quantity and quality characteristics of ammonia-nitrogen wastewater from ion-type rare earth mines were analyzed.The process technology characteristics of existing ion-type rare earth mine wastewater treatment engineering practices were compared,and theoretical cost analysis was conducted.Based on the analysis of the advantages and disadvantages of new biological nitrogen removal technologies such as Anammox in the treatment of ammonia-nitrogen wastewater from rare earth mines,a combined process of partial denitrification-partial nitrification-Anammox was proposed to improve the effluent quality and reduce energy,which was proved to be the best process for removing nitrogen from ammonia-nitrogen wastewater of ionic rare earth mines.

ion-type rare earth mineammonia-nitrogen wastewaterpartial denitrificationpartial nitrificationAnammox

范存文、郭佩洁、胡予佳、刘新福、邱清荣、苏昊、张大超

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江西理工大学资源与环境工程学院,江西 赣州 341000

赣州生态环境工程投资有限责任公司,江西 赣州 341000

离子型稀土矿山 氨氮废水 短程反硝化 短程硝化 厌氧氨氧化

2025

工业水处理
中海油天津化工研究设计院

工业水处理

北大核心
影响因子:0.737
ISSN:1005-829X
年,卷(期):2025.45(1)