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商混站污水的双铝电极电絮凝研究

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为实现商混站强碱性污水的无药剂高效絮凝沉降与澄清再生,提出了双铝电极电絮凝方法。通过正交试验考察了商混站污水浊度随电解时间、工作电压和电极配置模式的变化规律,并利用聚焦光束反射分析仪(FBRM)考察了3种因素对絮团弦长的影响。正交试验结果表明,工作电压对浊度的影响显著性最大,其次是电极配置模式,电解时间的影响显著性最小。通过对絮团弦长的分析可知,絮团尺寸和抗破碎强度均随工作电压的增大和电解时间的延长而增加,且单极并联模式(MP-P)下生成的絮团强度最大。当采用MP-P模式、工作电压30 V、电解时间15 min时,商混站污水的絮凝澄清效果最佳,污水浊度可降至69。8 NTU以下,浊度去除率可达93%以上,且絮团平均弦长增长速率最快,强度最大。相较于传统化学絮凝,电絮凝法可避免处理过程对循环水的二次污染,不会对混凝土的工艺性能产生不利影响,为商混站污水的科学高效净化回用提供了一种新方法。
Electrocoagulation of wastewater from commercial mixing stations with dual aluminum electrode
A dual aluminum electrode electrocoagulation method was proposed to achieve efficient flocculation settlement and clarification regeneration of strongly alkaline wastewater from commercial mixing station without agents.The turbidity variation of wastewater from commercial mixing stations with electrolysis time,operating volt-age,and electrode configuration mode was investigated through orthogonal experiments,and the effects of three fac-tors on floc chord length were examined using focused beam reflectance measurement(FBRM).The results of the or-thogonal experiments showed that the operating voltage had the greatest significance,followed by the electrode configuration mode,whereas the electrolysis time had the least significant impact.The analysis of flocculation chord length showed that the size and strength of the floc increased with the increase of operating voltage and electrolysis time,and the strength of flocs generated in the unipolar parallel mode(MP-P)was the highest.When using MP-P mode,operating voltage of 30 V,and electrolysis time of 15 min,the coagulation and clarification effect of wastewa-ter from commercial mixing station was the best.The turbidity of the wastewater could be reduced to below 69.8 NTU,and the turbidity removal rate could reach over 93%.In addition,the average chord length growth rate of the flocs was the fastest and the strength was the highest.Compared with traditional chemical flocculation,electroco-agulation could avoid secondary pollution of circulating water during the treatment process,and would not have ad-verse effects on the process performance of concrete,providing a new method for the scientific and efficient purifica-tion and reuse of wastewater from commercial mixing stations.

strongly alkaline wastewaterelectrocoagulationdual aluminum electrodeturbidityflocs chord length

倪宽、山晓莉、戚栋、李强、张文军

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中国矿业大学化工学院,江苏 徐州 221116

湖州上建华煜混凝土有限公司,浙江 湖州 313000

强碱性污水 电絮凝 双铝电极 浊度 絮团弦长

2025

工业水处理
中海油天津化工研究设计院

工业水处理

北大核心
影响因子:0.737
ISSN:1005-829X
年,卷(期):2025.45(1)