首页|三维荧光光谱技术结合PARAFAC指示含油废水处理过程中的有机质变化

三维荧光光谱技术结合PARAFAC指示含油废水处理过程中的有机质变化

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文章采用三维荧光光谱和平行因子技术,研究含油污水中的溶解性有机质经过生化处理后的组成特征及转化规律。结果表明,炼油废水以类色氨酸和类酪氨酸类荧光组分为主;生化处理后,出水的芳香族含量和腐殖化程度提升,同时类酪氨酸化合物被有效去除,而类色氨酸、类富里酸和类腐殖酸化合物则难以被去除;代表类酪氨酸的C1组分占比急剧降低,而代表类色氨酸的C3组分占比增加。其中,C3组分可作为指示废水中溶解性有机质变化的指标。
Three-dimensional Excitation Emission Matrix Fluorescence Spectroscopy Combined with PARAFAC Indicating the Changes in Organic Matter in the Process of Oily Wastewater Treatment
The composition characteristics and transformation rules of dissolved organic matter in oily wastewater after biochemical treatment were studied by three-dimensional excitation emission matrix fluorescence spectroscopy and PARAFAC.The results showed that the refinery wastewater was mainly composed of tryptophan-like and tyrosine-like fluorescent components.After biochemical treatment,the aromatic content and humification degree of the effluent increased,the tyrosine-like compounds were effectively removed,and the tryptophan-like,fulvic-like and humic-like compounds were difficult to be removed.The proportion of C1 component representing tyrosine decreased sharply and the proportion of C3 component representing tryptophan increased.Among them,the C3 component could be used as an indicator to indicate the change of dissolved organic matter in wastewater.

dissolved organic matterthree-dimensional excitation emission matrix fluorescence spectroscopyPARAFACrefinery wastewatercomposition transformation

何俊辉、卢显赫

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中海油能源发展股份有限公司工程技术分公司中海油实验中心,天津 300452

溶解性有机质 三维荧光光谱技术 平行因子分析 炼油废水 组成转化

2024

工业微生物
全国工业微生物信息中心 上海市工业微生物研究所

工业微生物

影响因子:0.293
ISSN:1001-6678
年,卷(期):2024.54(6)