首页|喀斯特地貌下历史遗留铅锌冶炼废渣对周边土壤重金属含量的影响

喀斯特地貌下历史遗留铅锌冶炼废渣对周边土壤重金属含量的影响

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以贵州某历史遗留铅锌冶炼废渣为研究对象,采集了铅锌冶炼废渣以及周边土壤,检测分析每种样品镉、汞、砷、铅、铬、铜、镍、锌的含量,采用单因子污染指数法和内梅罗综合污染指数法对铅锌冶炼废渣下游河流周边土壤环境质量进行了评价,研究铅锌冶炼废渣对周边土壤重金属含量的影响.结果发现:历史遗留铅锌冶炼废渣重金属镉、砷、铅含量较高,超过《土壤环境质量 农用地土壤污染风险管控标准(试行)》(GB 15618-2018)农用地土壤污染风险管制值,重金属铜、镍、锌超过农用地土壤污染风险筛选值.冶炼废渣周边土壤重金属镉、铜、镍含量较高,全部超农用地土壤污染风险筛选值,离废渣距离越远,土壤重金属含量先升后降,冶炼废渣河流左岸重金属污染程度大于右岸.从土壤重金属单因子污染指数来看,土壤重金属镉含量存在严重污染,其次为重金属铜>镍>铬>锌.从综合污染指数来看,土壤重污染区域占比 58%,中污染区域占比 42%.综上说明历史遗留的铅锌冶炼废渣对周围土壤环境存在安全隐患.
Influence of lead and zinc smelting waste on heavy metal content of surrounding soils under karst landscape
Taking a historical lead and zinc smelting site in Guizhou as the research object,we col-lected lead and zinc smelting slag as well as the surrounding soil,tested and analyzed the content of cadmium,mercury,arsenic,lead,chromium,copper,nickel and zinc of each sample,and evalua-ted the environmental quality of the soil around the river downstream of the lead and zinc smelting slag by using the Single Factor Pollution Index(SFPI)method and Nemerow Comprehensive Pollu-tion Index(NCPI)method to research the effect of the lead and zinc smelting site on the surrounding soil's heavy metal content.The results found that the cadmium,arsenic and lead content of the slag samples are high,exceeding the risk control value of agricultural land soil pollution in the"Soil En-vironmental Quality Agricultural Land Soil Pollution Risk Control Standards(Trial)"(GB 15618-2018),while copper,nickel and zinc exceeding the screening value of the risk of soil pollution in agricultural land.For the surrounding soil samples,cadmium,copper,nickel content are high,all ex-ceeding the agricultural land soil pollution risk screening value.As the distance from the slag becomes larger,the heavy metal content of the soil first rises and then falls.The left bank of the river is generally more affected by smelting slag than the right bank.From the point of view of single-factor pollution index of soil heavy metals,there is serious pollution of soil cadmium,and the degree of pollution is in the fol-lowing order:cadmium>copper>nickel>chromium>zinc.According to the comprehensive pollution index,heavy pollution soil area accounts for 58%,medium pollution area accounts for 42%.In summary,the historical left lead and zinc smelting slag shows certain degree of risk to the surrounding soil environment.

lead and zinc smelting waste residueheavy metalssoilenvironmental impact

杨雨嘉、李培林、刘庆玲、陈萍、唐黎

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贵州省环境科学研究设计院,贵阳 550081

贵阳市城市建设投资集团有限公司,贵阳 550000

铅锌冶炼废渣 重金属 土壤 环境影响

2024

环保科技
贵州省环境科学研究设计院

环保科技

影响因子:0.342
ISSN:1674-0254
年,卷(期):2024.30(3)