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离子排斥色谱法测定环境样品中挥发性有机酸及乳酸

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提出了同时测定环境样品中挥发性有机酸及乳酸的离子排斥色谱法(IEC法)。考察了流动相浓度、流速对有机酸分离的影响。实验结果表明,乳酸、甲酸、乙酸、丙酸、正丁酸和正戊酸可达到完全分离,被测组分的浓度与其峰高在一定的范围呈良好的线性关系,检出限均低于0.10 mg/L。测定了糖蜜酒精废水和消化污泥中有机酸的含量,结果满足检测的要求,样品中各组分的相对标准偏差为2.2%~5.6%。
Ion Exclusion Chromatography Method Determination of Volatile Organic Acids and Lactic Acid in the Environmental Samples
Volatile organic acids and lactic acid in the environmental samples were simultaneously determined by ion exclusion chromatography(IEC) method.The concentration and velocity of mobile phase were examined for the effects to the separation of organic acids.The results showed that lactic acid,formic acid,acetic acid,propionic acid,butyric acid and pentanoic acid were completely separated.The measured concentrations of organic acids showed good linear relationships with those peak heights in a certain range.The detection limits were less than 0.10 mg/L.The concentrations of organic acids in molasses alcohol waste and digested sludge were determined and the results met the testing requirements.The relative standard derivations were from 2.2% to 5.6%.

ion exclusion chromatography(IEC)lactic acidvolatile organic acidsmolasses alcohol wastedigested sludge

杨学灵、林瑛

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中国科学院广州化学研究所,广东广州510650

离子排斥色谱(IEC) 乳酸 挥发性有机酸 糖蜜酒精废水 消化污泥

2011

广州化学
中国科学院广州化学研究所

广州化学

影响因子:0.291
ISSN:1009-220X
年,卷(期):2011.36(3)
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