首页|聚吡咯包裹WO3-x纳米粒子的制备及光动力光热和杀菌性能

聚吡咯包裹WO3-x纳米粒子的制备及光动力光热和杀菌性能

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利用氯化钨和吡咯等原料通过溶剂热法和原位还原制备了聚吡咯包裹的WO3-x纳米粒子.用扫描电镜和红外光谱表征了复合材料,通过单线态氧生成能力、光热测试和体外杀菌实验,对比了聚吡咯包裹前后 WO3-x纳米粒子的光动力光热和杀菌性能.结果表明,得到的聚吡咯包裹的WO3-x纳米粒子复合材料在 808 nm照射下具有较好的单线态氧生成能力及光热性能.体外杀菌实验证明了其对革兰氏阳性菌和革兰氏阴性菌具有优秀的杀菌性能,对金黄色葡萄球菌和大肠杆菌的杀菌率分别为 99.89%和 99.71%.
Preparation and Photodynamic and Photothermal Bactericidal Properties of Polypyrrole-encapsulated WO3-X Nanoparticle
Polypyrrole-encapsulated WO3-x nanoparticles were prepared by solvothermal method and in situ reduction using raw materials such as tungsten chloride and pyrrole.The composites were characterised by scanning electron microscopy and infrared spectroscopy,and the bactericidal properties of polypyrrole-encapsulated WO3-x nanoparticles before and after polypyrrole encapsulation were compared by in vitro bactericidal assay,single-linear oxygen generation capacity and photothermal test.The results show that the obtained polypyrrole-encapsulated WO3-x nanoparticles composites have better single-linear oxygen generation capacity and photothermal performance under 808 nm irradiation.The in vitro bactericidal experiments demonstrated the excellent bactericidal properties against Gram-positive and Gram-negative bacteria,with 99.89%and 99.71%bactericidal rates against Staphylococcus aureus and Escherichia coli,respectively.

tungsten oxidepolypyrrolephotodynamicphotothermalsterilisation

祁星瑞、靳焘

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中国科学院广州化学研究所,广东 广州 510650

中国科学院大学,北京 100049

中科检测技术服务(广州)股份有限公司,广东 广州 510650

中国科学院新型特种精细化学品工程实验室,广东 广州 510650

国科广化韶关新材料研究院,广东 南雄 512400

国科广化(南雄)新材料研究院有限公司,广东 南雄 512400

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氧化钨 聚吡咯 光动力 光热 杀菌

2024

广州化学
中国科学院广州化学研究所

广州化学

影响因子:0.291
ISSN:1009-220X
年,卷(期):2024.49(1)
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