首页|电沉积法制备三种碳材料/导电聚合物复合涂层在金属双极板表面的应用进展

电沉积法制备三种碳材料/导电聚合物复合涂层在金属双极板表面的应用进展

扫码查看
简单介绍了质子交换膜燃料电池在酸性环境下金属双极板容易发生腐蚀,导致燃料电池输出效率降低的问题;概述了导电聚合物涂层在金属双极板表面的四种防腐机制,包括物理屏障机理、阳极保护、智能释放机理和电场屏蔽机理.以聚吡咯(PPY)、聚苯胺(PANI)为例,综述了近年来电沉积制备的碳纳米管、石墨烯和碳粉三种碳材料/导电聚合物复合涂层在金属双极板表面的应用,从制备方法、涂层材料、基底材料、测试环境、耐蚀性能和形貌对应用情况做总结对比.最后展望了碳材料/导电聚合物复合涂层面临的挑战和未来的要求.
Application Progress of Three Carbon Material/Conductive Polymer Composite Coating Prepared by Electrodeposition Method on Surface of Metal Bipolar Plates
The problem of metal bipolar plates of proton exchange membrane fuel cells being prone to corrosion in acidic environments is introduced in this paper,resulting in reduced fuel cell output efficiency.Four anti-corrosion mechanisms of conductive polymer coatings on the surface of metal bipolar plates are outlined,including physical barrier mechanism,anode protection,intelligent release mechanism and electric field shielding mechanism.Taking polypyrrole(PPY)and polyaniline(PANI)as examples,the application of three carbon materials/conductive polymer composite coatings on the surface of metal bipolar plates:carbon nanotubes,graphene,and carbon powder prepared by electrodeposition in recent years is reviewed in this paper.The application status from the preparation method,coating material,base material,test environment,corrosion resistance performance,and morphology is summarized and compared as well.Finally,the challenges and future requirements of carbon material/conductive polymer composite coatings are prospected.

electrodepositionmetal bipolar platecarbon materialconductive polymerpolyanilinepolypyrrolecorrosion protection

段育连、李静

展开 >

上海理工大学 材料与化学学院,上海 200093

电沉积 金属双极板 碳材料 导电聚合物 聚苯胺 聚吡咯 腐蚀防护

2024

广州化学
中国科学院广州化学研究所

广州化学

影响因子:0.291
ISSN:1009-220X
年,卷(期):2024.49(5)
  • 6