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地下水氯代烃原位氧化效果及腐蚀风险分析

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氯代烃污染地下水修复技术开发与应用一直是学术界研究的热点.通过小试实验获取了Fe2+和NaOH活化Na2S2O8 修复氯代烃的最优参数,利用高压旋喷技术进行工程实例应用,修复完成后,对地下水修复效果及潜在腐蚀风险进行评价.结果表明:NaOH活化Na2S2O8对氯乙烯的去除率较Fe2+活化更高,当过硫酸盐投加比为 2%时,可满足修复要求.工程修复后,地下水中氯乙烯、1,1,2-三氯乙烷和1,2-二氯乙烷浓度均低于修复目标值,且随时间延长均呈逐渐降低趋势,满足修复要求.从地下水pH值、ORP、残留的硫酸盐和氯化物浓度等角度对修复后地下水腐蚀风险进行分析表明腐蚀风险较低.
In Situ Oxidation Effect and Corrosion Risk Analysis of Groundwater Chlorinated Hydrocarbons
The development and application of chlorinated hydrocarbon contaminated groundwater remediation technology has been a hot topic in the academic field.The optimum parameters for re-pairing chlorinated hydrocarbons by activating Na2S2O8 with Fe2+and NaOH were obtained through a pilot experiment.The high pressure rotary jet technology was applied to an engineering example.After the restoration,the groundwater restoration effect and potential corrosion risk were evaluated.The results showed that the removal rate of vinyl chloride by NaOH activation of Na2S2O8 was higher than that by Fe2+activation,when the persulfate dosage was 2%,the repair re-quirement could be met.After the restoration,the concentrations of vinyl chloride,1,1,2-trichloro-ethane and 1,2-dichloroethane in groundwater were all lower than the restoration target values,and showed a gradually decreasing trend with the extension of time,which met the restoration require-ments.The analysis of groundwater corrosion risk from pH,ORP,residual sulfate and chloride con-centration showed that the corrosion risk is low.

in-situ chemical oxidationchlorinated hydrocarbonsgroundwater remediationeffect evaluationcorrosion risk

梁增强、宋文筠

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天津市环鉴环境检测有限公司,天津 300191

天津市环境污染损害鉴定评估中心,天津 300191

原位化学氧化 氯代烃 地下水修复 效果评估 腐蚀风险

2024

河北环境工程学院学报

河北环境工程学院学报

ISSN:
年,卷(期):2024.34(4)