河北工程大学学报(自然科学版)2024,Vol.41Issue(5) :95-102.DOI:10.3969/j.issn.1673-9469.2024.05.013

溶剂对Fe-MnOx催化剂的超低温NH3-SCR影响研究

Investigation of Solvents' Influences on Fe-MnOx Catalyst for Utra-low Temperature NH3-SCR

付祝跃 裴振昭 赵毅 许嘉淇 王海澎 张兴建
河北工程大学学报(自然科学版)2024,Vol.41Issue(5) :95-102.DOI:10.3969/j.issn.1673-9469.2024.05.013

溶剂对Fe-MnOx催化剂的超低温NH3-SCR影响研究

Investigation of Solvents' Influences on Fe-MnOx Catalyst for Utra-low Temperature NH3-SCR

付祝跃 1裴振昭 1赵毅 2许嘉淇 1王海澎 1张兴建1
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作者信息

  • 1. 河北工程大学 材料科学与工程学院,河北 邯郸 056038
  • 2. 河北威达蓝海环保科技股份有限公司,河北 邯郸 050071
  • 折叠

摘要

针对制备过程中溶剂环境的差异对Fe-MnOx 催化剂的影响问题,采用一步共沉淀法制备Fe-MnOx催化剂,探究了合成该催化剂过程中不同的溶剂环境对催化剂活性的影响,发现以甘油作为溶剂环境制备的催化剂有最佳的低温活性和抗硫能力.通过一系列的表征分析后发现,在甘油环境下制备的催化剂具有规则的颗粒形貌和颗粒尺寸、最大的比表面积、丰富且均匀分布的孔道结构、最高的Mn4+、Fe3+和Oα的含量,因而在50℃,GHSV=30000/h的条件下,表现出 80%以上的NOx脱除率和更好的抗硫能力.

Abstract

Aiming at the influence of different solvent environments on Fe-MnOx catalysts during the preparation process,Fe-MnOx catalysts were prepared by a one-step co-precipitation method.The inf-luence of different solvent environments on catalyst activity during the synthesis of the catalyst was investigated.It was found that the catalyst prepared by glycerol as a solvent environment had the best low-temperature activity and sulfur resistance.Through a series of characterization analyses,it was found that the catalyst prepared in a glycerol environment has regular particle morphology and particle size,the largest specific surface area,abundant and evenly distributed pore structure,and the highest contents of Mn4+,Fe3+and Oα.Therefore,under the condition of 50℃and GHSV=30000/h,the catalyst can be used to improve the quality of the catalyst.It shows more than 80%NOx removal rate and better sulfur resistance.

关键词

一步共沉淀法/超低温/NH3-SCR/Fe-MnOx催化剂/溶剂

Key words

one-step co-precipitation method/ultra-low-temperature/NH3-SCR/Fe-MnOx catalyst/sol-vent

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基金项目

国家自然科学基金资助项目(22108054)

出版年

2024
河北工程大学学报(自然科学版)
河北工程大学

河北工程大学学报(自然科学版)

CSTPCD
影响因子:0.543
ISSN:1673-9469
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