河北科技师范学院学报2024,Vol.38Issue(3) :50-58.DOI:10.3969/J.ISSN.1672-7983.2024.03.008

改性生物炭对海水中磺胺嘧啶的吸附性能

A Study on the Adsorption Performance of Modified Biochar on Sulfadiazine in Seawater

胡峥嵘 陈俊 李瑞鹏 王星 宋爱君 王月辉 张志伟 鲁勖琳 沈莉 吉国佳 侯春亮 张晶梅
河北科技师范学院学报2024,Vol.38Issue(3) :50-58.DOI:10.3969/J.ISSN.1672-7983.2024.03.008

改性生物炭对海水中磺胺嘧啶的吸附性能

A Study on the Adsorption Performance of Modified Biochar on Sulfadiazine in Seawater

胡峥嵘 1陈俊 1李瑞鹏 1王星 1宋爱君 1王月辉 1张志伟 1鲁勖琳 1沈莉 1吉国佳 1侯春亮 1张晶梅1
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作者信息

  • 1. 河北科技师范学院化学工程学院,河北秦皇岛,066600
  • 折叠

摘要

通过磷酸-氨水改性法对稻壳生物炭进行了化学修饰,制备改性生物炭(NPBC),并通过X射线衍射仪、场发射扫描电子显微镜、X射线光谱仪等方法对其物相、形貌及元素进行了表征.以海水中的磺胺嘧啶(SDZ)作为目标污染物,研究了 SDZ浓度、NPBC投加量及海水成分(NaCl、MgCl2、Na2SO4、CaCl2、KC1)对生物炭吸附性能的影响,并探究了吸附过程的吸附动力学.结果表明,SDZ的质量浓度为10mg·L-1,NPBC投加为0.4 g·L-1时吸附效果最好.研究表明,海水中的物质对吸附产生了阻碍作用,其中NaCl、MgCl2、GaCl2的影响分别占21.62%、15.72%、14.94%;吸附实验在120 min内达到平衡,最大吸附量为6.71 mg·g-1,吸附过程更符合准二级动力学方程.

Abstract

Modified biochar(NPBC)was prepared with phosphoric acid-ammonia modification method,and its phase,morphology and elements were characterized with X-ray diffraction,field emission scanning electron microscopy and X-ray spectrometer.The effects of SDZ concentration,NPBC dosage and seawater components(NaCl,MgCl2,Na2SO4,CaCl2,KC1)on the adsorption performance of biochar were studied,and the adsorption kinetics of the adsorption process were explored.The results showed that the adsorption effect was best when the concentration of SDZ was 10 mg·L-1 and the addition of NPBC was 0.4 g·L-1.The substances in seawater hindered adsorption and the effects of NaCl,MgCl2 and GaCl2 accounted for 21.62%,15.72%and 14.94%,respectively.The adsorption experiment reached equilibrium within 120 min,and the maximum adsorption capacity was 6.71 mg·g-1 which was more in line with the quasi-second-order kinetic equation.A new way for the removal of sulfonamide antibiotics from seawater is provided.

关键词

改性生物炭/吸附性能/磺胺嘧啶/吸附动力学

Key words

Modified biochar/adsorption properties/sulfadiazine/adsorption kinetics

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出版年

2024
河北科技师范学院学报
河北科技师范学院

河北科技师范学院学报

影响因子:0.414
ISSN:1672-7983
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