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脲醛树脂前驱体碳微球形貌调控及电化学性能研究

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为了探究原料配比对脲醛树脂形貌及碳微球电化学性能的影响,通过改变尿素、甲醛与甲酸的物质的量比,制备了三种不同微纳结构的脲醛树脂微球,再在氮气保护下800℃裂解,获得了相应的碳微球.采用上述脲醛树脂前驱体制备的花状碳纳米微球(NUFC-3)作为电极材料,在三电极体系中开展电化学性能研究.结果表明,在1 A/g的电流密度下,比电容(Cs)为189 F/g;在20 A/g的电流密度下,Cs为145 F/g,其保留率为76.7%.该脲醛树脂为前驱体的碳微球具有制备方法简单、成本低廉及电化学性能优异等优点,有望在电化学储能领域获得应用.
Morphology Control and Electrochemical Properties of Carbon Microspheres from Urea-formaldehyde Resin Precursors
In order to investigate the effects of raw materials ratio on the morphology of urea formaldehyde resin and the electrochemical performance of carbon microspheres,three kinds of urea-formaldehyde resin microspheres with different micro/nano structures were prepared by changing the amount of substance ratio of urea,formalde-hyde and formic acid,after that,the corresponding carbon microspheres were obtained by pyrolysis at 800 ℃ un-der nitrogen protection.The flower-like carbon nanospheres(NUFC-3)prepared by the above urea-formaldehyde resin precursor were used as electrode materials,and the NUFC-3 showed good electrochemical performance in the three-electrode system.The results show that the specific capacitance(Cs)is 189 F/g at a current density of 1 A/g;the Cs is 145 F/g at a current density of 20 A/g,and the retention rate of Cs is 76.7%.The carbon micro-spheres prepared by the precursor of urea formaldehyde resin have many advantages like simple preparation meth-od,low cost and good electrochemical performance,which are expected to be applied in the field of electrochemi-cal energy storage.

urea-formaldehyde resincarbon microspheresmorphology controlelectrochemical propertiessuper-capacitors

任广元、胡绍纲、吴云轩、艾军鹏

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东华理工大学化学与材料学院,江西南昌 330013

脲醛树脂 碳微球 形貌调控 电化学性能 超级电容器

2024

东华理工大学学报(自然科学版)
东华理工学院

东华理工大学学报(自然科学版)

北大核心
影响因子:0.634
ISSN:1674-3504
年,卷(期):2024.47(1)