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江西省近地面臭氧污染特征及成因分析

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基于2015-2020年江西省11设区市臭氧(O3)浓度数据、其他气态污染物和气象资料,利用数理统计方法分析自"大气污染防治行动计划"和"打赢蓝天保卫战三年行动计划"以来江西近地面O3时空污染特征及其成因.结果表明,江西O3日最大8小时浓度(O3 MDA8)年均增长率为3.95%,浓度增长2.57 μg/(m3·a),O3在5、9月达到峰值,O3小时浓度在15:00达到峰值;11设区市中鹰潭O3 MDA8浓度最高(147.6 μg/m3),而新余增幅最大(9.94%);利用方差分析和Spearman相关性分析发现日照长、高温、低湿、少雨、低压等气象条件下易促进O3积累;污染天时,O3 MDA8、光化学总氧化剂浓度和日照分别是清洁天的2.13倍、1.79倍和2.22倍,O3与其前体物NO2、CO等呈正相关,与相对湿度(RH)、降水量呈显著负相关,表明O3污染受大气氧化性、前体物排放和气象因子(日照、RH和降水量)等影响较大.
Analysis on Characteristics and Causes of Ground-level Ozone Pollution in Jiangxi Province
It was studied based on the ozone hour data of 11 urban districts in Jiangxi province from 2015 to 2020 that the temporal and spatial characteristics of ground-level ozone(O3)in Jiangxi province since the ten-point plan of action on the prevention and control of air pollution and the three-year action plan for winning the blue sky defense.Analysis on ozone pollution causes was discussed in combination with other gaseous pollutants and mete-orological factors by using mathematical statistics analyses.The results showed that the average annual growth rate of O3 MDA8 in Jiangxi province was 3.95%,and the concentration increased by 2.57 pg/(m3·a).Monthly variations of O3 MDA8 concentrations reached the peak in May and September,respectively.The hour ozone con-centrations peaked at 15:00.The average annual concentration of O3 MDA8 was the highest in Yingtan among 11 cities with a value of 147.6 μg/m3.But the increment was the largest in Xinyu,whose value was 9.94%.It was found that O3 accumulation was easily promoted under meteorological conditions such as long sunshine time,high temperature,low relative humidity(RH),little rain,and low pressure by analysis of variance and Spearman cor-relation analysis.The concentrations of O3 MDA8,photochemical total oxidant,and sunlight hours were 2.13 times,1.79 times and 2.22 times on the polluted day of that on the clean day,respectively.Ozone was positively correlated with O3 precursors(for example NO2 and CO),while it was significantly negatively correlated with RH and precipitation.These results indicated that O3 pollution was greatly affected by atmospheric oxidation,O3 pre-cursor emissions,and meteorological factors(such as sunshine,RH,and precipitation).

O3temporal and spatial characteristicsgaseous pollutantsmeteorological factorsatmospheric oxi-dation

方小珍、刘诚、邓力琛、钱悦、冯钰

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东华理工大学水资源与环境工程学院,江西南昌 330013

东华理工大学江西省大气污染成因与控制重点实验室,江西南昌 330013

江西省生态气象中心,江西南昌 330096

O3 时空污染特征 气态污染物 气象因素 大气氧化性

2024

东华理工大学学报(自然科学版)
东华理工学院

东华理工大学学报(自然科学版)

北大核心
影响因子:0.634
ISSN:1674-3504
年,卷(期):2024.47(4)