首页|流动条件下铁基非晶纳米晶涂层钝化行为研究

流动条件下铁基非晶纳米晶涂层钝化行为研究

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通过初期腐蚀电流密度监测、电化学阻抗谱、极化曲线和微观形貌分析,研究了静态和动态不同流速下铁基非晶纳米晶涂层的钝化与点蚀行为.结果表明:流动条件下,铁基非晶纳米晶涂层的自腐蚀倾向增加;随着流速的增加,钝化电流密度先增加后减小,流速为5 L/min时,钝化电流密度达到极大值3.09×10-4 A/cm2;点蚀电位先降低后增加,滞后环面积先增加后减小,点蚀坑最大深度达50.61 μm,可见高流速条件下涂层的点蚀能力降低.
Study on Passivation Behavior of Fe-based Amorphous Nanocrystalline Coatings under Flow Conditions
Through monitoring the density of initial corrosion current,analyzing electrochemical impedance spectrum,polarization curve and micro-morphology,both corrosion tendency and pitting behavior of Fe-based amorphous nanocrystalline coatings at different flow rates were studied to show that,the self-corro-sion tendency of Fe-based amorphous nanocrystal coatings increases under flow conditions.With the in-crease of the flow rate,the passivation current density increases first and then decreases and reaches 3.09×10-4 A/cm2,a maximum value when the flow rate stays at 5 L/min.The pitting potential decreases first and then increases and the hysteresis ring area increases first and then decreases and the maximum depth of pitting pit reaches 50.61 μm.This means that the pitting ability of the coating decreases at high flow rate.

Fe-based amorphous nanocrystalline coatingsdynamic corrosionflow ratepassivationpitting corrosion

王勇、王书然、史安邦、衣方宇、王宇航、李梓依

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东北石油大学机械科学与工程学院

中国石油集团长城钻探工程有限公司

铁基非晶纳米晶涂层 动态腐蚀 流速 钝化 点蚀

国家自然科学基金黑龙江省自然科学基金

51974091LH2023E016

2024

化工机械
天华化工机械及自动化研究设计院有限公司

化工机械

CSTPCD
影响因子:0.325
ISSN:0254-6094
年,卷(期):2024.51(4)
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