化工机械2024,Vol.51Issue(6) :854-863,903.DOI:10.20031/j.cnki.0254-6094.202406008

超临界二氧化碳去除铁尾矿中的重金属

Removing Heavy Metals from Iron Tailings through Supercritical Carbon Dioxide

汪明星 刘胜敏 刘畅 曾祥荣 廖传华 廖佳凯 陈琳
化工机械2024,Vol.51Issue(6) :854-863,903.DOI:10.20031/j.cnki.0254-6094.202406008

超临界二氧化碳去除铁尾矿中的重金属

Removing Heavy Metals from Iron Tailings through Supercritical Carbon Dioxide

汪明星 1刘胜敏 1刘畅 1曾祥荣 1廖传华 1廖佳凯 2陈琳2
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作者信息

  • 1. 南京工业大学机械与动力工程学院
  • 2. 南京三方化工设备监理有限公司
  • 折叠

摘要

铁尾矿含有Pb、Cu、Cr、Zn等重金属,没有经过处理就大量堆积,会造成严重的重金属污染.超临界二氧化碳萃取技术可在短时间内对多种重金属同时实现高效去除.研究以乙醇作为夹带剂,使用磷酸三丁酯(A)和二乙基二硫代氨基甲酸钠(B)作为络合剂在最佳条件下,Pb、Cu、Cr、Zn的最大去除率分别为88.28%、47.63%、65.58%、67.25%.同时,通过Gaussian模拟软件分别探讨了两种络合剂去除尾矿中重金属的机理.

Abstract

Iron tailings with heavy metals such as Pb,Cu,Cr and Zn accumulate in large quantities with-out treatment and they result in serious heavy metal pollution.Supercritical CO2 extraction technology can simultaneously and efficiently remove multiple heavy metals in a very short time.In this study,the maxi-mum removal rates of Pb,Cu,Cr and Zn are 88.28%,47.63%,65.58%and 67.25%,respectively when taking ethanol as the entrainment agent and tributyl phosphate(A)and diethyldithiocarbamate sodium(B)as the complexing agent under the optimal conditions;meanwhile,through making use of Gaussian simula-tion software,the mechanism of removing heavy metals from tailings by two complexing agents was dis-cussed.

关键词

超临界二氧化碳/重金属/Gaussian模拟

Key words

supercritical CO2/heavy metals/Gaussian simulation

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出版年

2024
化工机械
天华化工机械及自动化研究设计院有限公司

化工机械

CSTPCD
影响因子:0.325
ISSN:0254-6094
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