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聚甲醛生产废液连续精馏回收工艺的模拟优化

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基于聚甲醛生产废液成分及特性,提出聚甲醛有机废液回收三塔精制工艺,采用软件对工艺以最小TAC进行模拟优化,确定最优工艺条件为:甲酸甲酯精馏塔的塔理论板数为 54,回流比为 3。002,进料位置为 45,水洗塔的萃取剂水的用量比为 0。5,回流比为1。0253,理论板数为 18,进料位置为 16,萃取剂进料板位置为 6。脱甲醇塔回流比为 4。1,塔板数 50,进料板位置为 43,其最小TAC为3。02×106 ¥/y。通过热泵技术对脱甲醇塔进行过程强化,再沸器的能耗下降了 38。1%,TAC下降了 8。75×105 ¥/y。研究为聚甲醛废液连续精馏回收过程的设计提供了参考。
Simulation and Optimization of Continuous Rectification Process for Polyoxymethylene Waste Liquid
Proposes a three-tower refining process for the recovery of polyformaldehyde organic waste liquid,based on its composition and characteristics.The process was simulated and optimized using software to minimize total area content(TAC).The optimal conditions were determined as follows:The theoretical plate number for the methyl formate distillation tower was 54,the reflux ratio was 3.002,the feed position was 45,the water consumption ratio of the extractant in the water washing tower was 0.5,the reflux ratio was 1.0253,the theoretical plate number was 18,the feed position was 16,and the extractant feed plate position was 6.The de-methanolization tower had a reflux ratio of 4.1,a plate number of 50,and a feed plate position of 43,with a minimum TAC of 3.02×106 ¥/y.By employing heat pump technology to enhance the de-methanolization tower process,the energy consumption of the reboiler decreased by 38.1%,and the TAC decreased by 8.75×105 ¥/y.The research provides a valuable reference for the design of continuous distillation recovery processes for polyformaldehyde waste liquid.

paraformaldehydeorganic waste streamrecoverysequence optimization methodheat pump distillation

彭亮亮、刘彪、朱永宏、项栋、鲁一哲、王强

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新疆国业新材料科技有限公司 新疆 830014

新疆大学化工学院 新疆 830017

聚甲醛 有机废液 回收 序列优化法 热泵精馏

2025

当代化工研究
中国化工报社

当代化工研究

影响因子:0.294
ISSN:1672-8114
年,卷(期):2025.(1)