首页|改性土壤的制备及其对Hg2+的吸附性能研究

改性土壤的制备及其对Hg2+的吸附性能研究

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为了经济高效地脱除废水中的重金属汞离子,制备改性土壤作为Hg2+的优良吸附剂。利用 5 种酸性活化剂对土壤进行改性,发现用体积分数为 0。3%的HNO3 洗涤后改性土壤对Hg2+的吸附性能较好。Freundlich方程很好地描述了改性土壤对Hg2+的吸附等温线,改性土壤在进行Hg2+吸附时,最佳pH值为 9。在动力学分析中发现,伪二阶动力学方程更加符合改性土壤对Hg2+的吸附过程。对改性土壤进行脱附再生实验后发现,HCl和乙醇分段式的脱附方式吸附效率最高,达到62。79%。
Preparation of Modified Soil and Study on Its Adsorption Properties for Hg2+
To cost-effectively remove heavy metal mercury ions from wastewater,modified soil was prepared as an excellent adsorbent for Hg2+.Five acidic activators were used to modify the soil,and it was found that the modified soil after washing with 0.3%HNO3 exhibited superior adsorption performance for Hg2+.The Freundlich equation accurately described the adsorption isotherm of the modified soil for Hg2+.The optimal pH for the adsorption of Hg2+by the modified soil was 9.In kinetic analysis,it was discovered that the pseudo-second-order kinetic equation more closely fit the adsorption process of the modified soil for Hg2+.After conducting desorption regeneration experiments on the modified soil,it was dis-covered that the segmented desorption method using HCl and ethanol achieved the highest adsorption efficiency of 62.79%.

modified soilstatic adsorptionheavy metalsadsorption kinetics

王露、邵延海、张龚丹

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昆明理工大学 国土资源工程学院 云南 650093

黄冈市固体废物污染防治中心 湖北 438000

黄冈生态环境监测中心 湖北 438000

改性土壤 静态吸附 重金属 吸附动力学

2025

当代化工研究
中国化工报社

当代化工研究

影响因子:0.294
ISSN:1672-8114
年,卷(期):2025.(1)