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芬顿氧化深度处理厌氧氨氧化出水影响因素的最优组合

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利用正交试验对影响芬顿氧化深度处理垃圾渗滤液厌氧氨氧化出水的起始 pH、nFe2+/nH2O2、mH2O2/mCODcr、反应温度 4种主要因素的最优组合开展研究。结果表明:4种因素均对芬顿氧化深度处理垃圾渗滤液厌氧氨氧化出水产生显著影响,影响顺序为起始pH>反应温度>mH2O2/mCODCr>nFe2+/nH2O2,起始pH对CODCr去除率影响极显著,mH2O2/mCODCr和 nFe2+/nH2O2 影响程度较为接近;4种影响因素最优组合为起始 pH=4。0、nFe2+/nH2O2=1:3、mH2O2/mCODCr=4:1、反应温度=20℃,该条件下CODCr和色度去除率高达 92。4%和 99。1%,出水可生化性好,处理效果达到工程应用要求,可为该联用系统的芬顿处理段提供一定的技术支撑。
Optimal combination of influencing factors for advanced treatment of anaerobic ammonia oxidation effluent by Fenton oxidation
The orthogonal test was used to study the optimal combination of four main factors affecting the initial pH,nFe2+/nH2O2,mH2O2/mCODcr and reaction temperature of anaerobic ammonia oxidation effluent of landfill leachate advanced treatment by Fenton oxidation.The results showed that all four factors had significant effects on the anaerobic ammonium oxidation effluent of landfill leachate treated by Fenton oxidation.The order of influence is initial pH>reaction temperature>mH2O2/mCODCr>nFe2+/nH2O2.The initial pH has a significant effect on the removal rate of CODCr.The influence degree of mH2O2/mCODCr and nFe2+/nH2O2 is close.The optimal combination of the four influencing factors is initial pH = 4.0,nFe2+/nH2O2 = 1:3,mH2O2/mCODCr = 4:1,reaction temperature = 20℃.Under this condition,the removal rates of CODCr and chroma are as high as 92.4%and 99.1%.The effluent has good biodegradability and the treatment effect meets the requirements of engineering application.It can provide some technical support for the Fenton treatment section of the combined system.

Fenton oxidationLandfill leachateanaerobic ammonium oxidationoptimal combination

陈福坤、邓海涛、陆冬云、吴琴琴、李琴

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广西生态工程职业技术学院,柳州 545004

广西春晖环保工程有限责任公司,柳州 545000

芬顿氧化 垃圾渗滤液 厌氧氨氧化 最优组合 正交试验

广西壮族自治区高等学校中青年教师科研基础能力提升项目广西生态工程职业技术学院自然科学研究项目

2021KY12122022ZRKX02

2024

环境保护科学
沈阳环境科学研究院

环境保护科学

CSTPCD
影响因子:0.469
ISSN:1004-6216
年,卷(期):2024.50(2)
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