首页|改性活性炭对水中硝基苯吸附特性影响研究

改性活性炭对水中硝基苯吸附特性影响研究

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选取压块破碎活性炭为研究对象,分别研究硝酸、浓硫酸、氢氟酸和氨水改性对活性炭表面官能团及元素组分的影响,以及改性前后活性炭对选定污染物的吸附性质的变化。实验结果表明,经氨水、氢氟酸以及硫酸改性后的活性炭对硝基苯吸附能力相似,且其在相同平衡浓度条件下,吸附容量较未改性活性炭略有改善;但经浓硝酸改性后,活性炭吸附性能明显下降,特别是浓硝酸改性后,下降明显。因此,活性炭对有机物的吸附以范德华力为主,增加表面官能团不能增加活性炭对硝基苯等有机污染物的吸附容量。
Study on the effect of modified activated carbon on adsorption characteristics of nitrobenzene in water
Taking briquette-activated carbon as the research object,the effects of modification with nitric acid,concentrated sulfuric acid,hydrofluoric acid and ammonia water on the surface functional groups and elemental components of activated carbon,and the changes of adsorption properties of activated carbon to selected pollutants before and after modification were studied respectively.The results showed that the adsorption capacity of nitrobenzene on activated carbon modified by ammonia,hydrofluoric acid and sulfuric acid was similar,and its adsorption capacity was slightly improved compared with that of unmodified activated carbon under the same equilibrium concentration.However,the adsorption performance of activated carbon decreased obviously after modification with concentrated nitric acid,especially after modification with concentrated nitric acid.Therefore,the adsorption of organic matter by activated carbon was mainly van der Waals force,and the adsorption capacity of activated carbon for nitrobenzene and other organic pollutants could not be increased by increasing surface functional groups.

activated carbonsurface modificationadsorption isothermfunctional groupnitrobenzene

王哲、林朋飞、马成业、杨国栋、张肖锦

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国家能源集团新疆能源有限责任公司,乌鲁木齐 830014

清华苏州环境创新研究院,苏州 215163

苏州科技大学,苏州 215009

活性炭 表面改性 吸附等温线 官能团 硝基苯

&&山东省重点研发计划

新疆能源科技[2021]17号2020CXGC011406

2024

环境保护科学
沈阳环境科学研究院

环境保护科学

CSTPCD
影响因子:0.469
ISSN:1004-6216
年,卷(期):2024.50(3)
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