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小麦粉中微塑料的鉴别研究

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为了探究小麦粉中微塑料的鉴别方法,该研究基于显微傅里叶变换红外光谱,首先优化了检测模式和消解溶液,考察了消解前后常见的 4种塑料(聚乙烯、聚丙烯、尼龙 6和聚苯乙烯)的耐受性,其次对市售小麦粉中微塑料的成分进行定性分析,解析了小麦粉样品中微塑料的丰度及污染途径.结果表明:(1)小麦粉样品中共挑选出 288个疑似微塑料物质,平均长度(912±527)μm.定性鉴别出的成分为聚酯、纤维素类物质、聚丙烯和尼龙 6,鉴别物质以聚酯和纤维素类物质为主,其中聚酯占 21.5%,纤维素类物质占 52.4%.(2)挑选出以透明和蓝色为主的疑似微塑料物质,分别占比54.2%和 22.6%.透明物质中的聚酯占 29.0%,纤维素类物质占 43.5%;蓝色物质中的聚酯占 16.9%,纤维素类物质占44.6%.表明小麦粉微塑料污染来源可能与人类日常活动及包装材料.该研究首次对小麦粉中微塑料定性鉴别研究,其方法适用于20 μm以上的以上4种微塑料的定性,有助于评估小麦粉中微塑料暴露对人体的健康风险.
Identification of microplastics in wheat flour
To investigate the identification of microplastics in wheat flour,the study was based on micro Fourier infrared spectroscopy.Firstly,the detection mode and digestion solution were optimized,and the tolerance of 4 common plastics(polyethylene,polypropylene,nylon 6,and polystyrene)before and after digestion.Additionally,the composition of microplastics in commercially available wheat flour was analyzed,the abundance and contamination pathways of microplastics in the wheat flour samples were analyzed.The results showed that:(1)A total of 288 suspected microplastic substances were identified in the wheat flour samples,with an average length of(912±527)μm.The qualitatively identified compositions were polyester,cellulosic,polypropylene,and nylon 6.The identified substances were dominated by polyester and cellulosic,of which polyester accounted for 21.5%,and cellulosic accounted for 52.4% .(2)Suspected microplastic substances,predominantly transparent and blue color were selected,accounting for 54.2% and 22.6%,respectively.In the transparent materials,polyester comprised 29.0%,while cellulosic made up 43.5%;In the blue materials,polyester accounted for 16.9%,and cellulosic constituted 44.6% .It was suggested that the source of microplastic contamination in wheat flour may be linked to human daily activities and packaging materials.The study represented the first qualitative identification of microplastics in wheat flour,with methods applicable to characterizing the 4 types of microplastics larger than 20 μm,which was helpful to evaluate the health risk of microplastics exposure in wheat flour.

microplasticsidentificationwheat flourμFTIR

张冰、朱琳、张蕊、郭宝元

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国家粮食和物资储备局科学研究院,北京 100037

微塑料 定性鉴别 小麦粉 显微傅里叶变换红外光谱

中央级公益性科研院所基本科研业务费专项资金资助

ZX2209

2024

环境保护科学
沈阳环境科学研究院

环境保护科学

CSTPCD
影响因子:0.469
ISSN:1004-6216
年,卷(期):2024.50(5)