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聚合硅酸镧絮凝剂的制备及其在高浊水中的深度除磷应用

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针对高浊污水深度处理中聚合氯化铝除磷低效问题,设计出一种新型高效除磷剂-聚合硅酸镧(PLSC).样品表征数据显示,聚合硅酸分子结构中部分硅被镧取代形成La-OH和Si-OLa基团,对磷去除效果进一步强化.实验数据结果显示,在高浊水中PLSC深度除磷时pH、温度、离子强度等适用范围广,呈现出高效除磷行为.利用FTIR、Zeta电位和SEM-EDS手段分析PLSC除磷机理,探讨发现PLSC表面La-OH对磷具有极强吸附作用,其中La与P络合方式主要以双齿双核为主.当高岭土存在时La与P络合方式由双齿双核向单齿单核转变,促进PLSC对磷去除效果.
Synthesis of polymerized lanthanum silicate flocculant for deep phosphate removal in high turbidity water
In view of the low efficiency of phosphate removal by polyaluminum chloride in the advanced treatment of high turbidity wastewater,a new efficient phosphorus removal agent-polymerized lanthanum silicate(PLSC),was designed.The characterization data showed that the part of silicon atoms in the molecular structure of polymerized silicic acid was replaced by lanthanum atoms to form the La-OH and Si-O-La groups,which further enhanced the phosphate removal efficiency.The experimental results showed that the pH,temperature and ionic strength of PLSC deep phosphorus removal in high turbidity water had a wide application range,showing high efficiency phosphorus removal behavior.The mechanism of phosphate removal by PLSC was analyzed by FTIR,Zeta potential and SEM-EDS,indicating that the La-OH group on the PLSC surface had a strong adsorption interaction on the phosphate,and the complexation mode of La-P was mainly double-toothed and double-nucleated.In the presence of kaolin,the complexation mode of La-P changed from two-tooth two-core to single-tooth single-core,which promoted the phosphate removal by PLSC.

PLSCcoagulationdeep phosphate removalkaolinhigh turbidity water

李文涛、吴晓梅、郑炎然、龚美佳、方宜宜、李杨、肖峰、夏志林、钟润生

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深圳信息职业技术学院,深圳 518172

华北电力大学,北京 102206

深圳市长隆科技有限公司,深圳 518000

聚合硅酸镧 絮凝 深度除磷 高岭土 高浊水

深圳市校企合作项目深圳市科技计划项目

SZIIT2021KJ02620220820003755001

2024

环境保护科学
沈阳环境科学研究院

环境保护科学

CSTPCD
影响因子:0.469
ISSN:1004-6216
年,卷(期):2024.50(5)