环境保护科学2024,Vol.50Issue(5) :150-156,162.DOI:10.16803/j.cnki.issn.1004-6216.202309022

聚合硅酸镧絮凝剂的制备及其在高浊水中的深度除磷应用

Synthesis of polymerized lanthanum silicate flocculant for deep phosphate removal in high turbidity water

李文涛 吴晓梅 郑炎然 龚美佳 方宜宜 李杨 肖峰 夏志林 钟润生
环境保护科学2024,Vol.50Issue(5) :150-156,162.DOI:10.16803/j.cnki.issn.1004-6216.202309022

聚合硅酸镧絮凝剂的制备及其在高浊水中的深度除磷应用

Synthesis of polymerized lanthanum silicate flocculant for deep phosphate removal in high turbidity water

李文涛 1吴晓梅 1郑炎然 1龚美佳 1方宜宜 1李杨 1肖峰 2夏志林 3钟润生1
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作者信息

  • 1. 深圳信息职业技术学院,深圳 518172
  • 2. 深圳信息职业技术学院,深圳 518172;华北电力大学,北京 102206
  • 3. 深圳市长隆科技有限公司,深圳 518000
  • 折叠

摘要

针对高浊污水深度处理中聚合氯化铝除磷低效问题,设计出一种新型高效除磷剂-聚合硅酸镧(PLSC).样品表征数据显示,聚合硅酸分子结构中部分硅被镧取代形成La-OH和Si-OLa基团,对磷去除效果进一步强化.实验数据结果显示,在高浊水中PLSC深度除磷时pH、温度、离子强度等适用范围广,呈现出高效除磷行为.利用FTIR、Zeta电位和SEM-EDS手段分析PLSC除磷机理,探讨发现PLSC表面La-OH对磷具有极强吸附作用,其中La与P络合方式主要以双齿双核为主.当高岭土存在时La与P络合方式由双齿双核向单齿单核转变,促进PLSC对磷去除效果.

Abstract

In view of the low efficiency of phosphate removal by polyaluminum chloride in the advanced treatment of high turbidity wastewater,a new efficient phosphorus removal agent-polymerized lanthanum silicate(PLSC),was designed.The characterization data showed that the part of silicon atoms in the molecular structure of polymerized silicic acid was replaced by lanthanum atoms to form the La-OH and Si-O-La groups,which further enhanced the phosphate removal efficiency.The experimental results showed that the pH,temperature and ionic strength of PLSC deep phosphorus removal in high turbidity water had a wide application range,showing high efficiency phosphorus removal behavior.The mechanism of phosphate removal by PLSC was analyzed by FTIR,Zeta potential and SEM-EDS,indicating that the La-OH group on the PLSC surface had a strong adsorption interaction on the phosphate,and the complexation mode of La-P was mainly double-toothed and double-nucleated.In the presence of kaolin,the complexation mode of La-P changed from two-tooth two-core to single-tooth single-core,which promoted the phosphate removal by PLSC.

关键词

聚合硅酸镧/絮凝/深度除磷/高岭土/高浊水

Key words

PLSC/coagulation/deep phosphate removal/kaolin/high turbidity water

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基金项目

深圳市校企合作项目(SZIIT2021KJ026)

深圳市科技计划项目(20220820003755001)

出版年

2024
环境保护科学
沈阳环境科学研究院

环境保护科学

CSTPCD
影响因子:0.469
ISSN:1004-6216
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