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飞灰水洗液处理工艺及其资源化利用研究进展

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水洗法作为城市生活垃圾焚烧飞灰的预处理方法被广泛采用,有利于飞灰的进一步固化/稳定化处理或资源化回收,飞灰水洗液中含有大量氯盐和微量重金属,直接排放会产生严重的环境问题,优化飞灰水洗液的处理工艺以及实现水洗液资源化利用已成为行业绿色发展的必然趋势.文章简要介绍了飞灰水洗液的来源、成分、危害等特点,针对飞灰水洗液中存在的大量氯盐和微量重金属成分,阐述了以下处理方法:采用化学沉淀法去除水洗液中的重金属成分;采用反渗透法、蒸发结晶、电渗析等方法去除飞灰水洗液中氯盐.进一步提出了水洗液资源化利用途径,即可从水洗液中回收氯化钠、氯化钾等氯盐,通过二氧化碳矿化反应来沉淀碳酸钙.该综述可为绿色、可持续的飞灰水洗液处理工艺提供理论参考.
Research progress on treatment technology and resource utilization of waste solution used in fly ash water-washing
The water-washing method is widely used as a pretreatment method for fly ash incinerated by municipal solid waste,which is conducive to further solidification/stabilization treatment or resource recovery of fly ash.The water-washing of fly ash contains many chlorides and trace heavy metals,and direct discharge will cause serious environmental problems.Optimizing the treatment process of fly ash water-washing solution and realizing the resource utilization of water lotion has become the industry's inevitable trend of green development.The source,composition and hazard of fly ash liquid were briefly overviewed.In view of the large amount of chlorine salts and trace heavy metals in fly ash liquid,the following treatment methods were described:chemical precipitation method was adopted to remove heavy metals from the liquid.The methods of reverse osmosis,evaporation crystallization and electrodialysis were used to remove chlorine salts from fly ash washing.The way of resource utilization of water washing solution as put forward,which could recover sodium chloride,potassium chloride and other chlorides from water wash solution and precipitate calcium carbonate through carbon dioxide mineralization reaction.It was expected to provide a theoretical reference for green and sustainable fly ash water-washing solution treatment processes.

fly ashchloridesheavy metalwaste water treatmentresource utilization

何玉清、张佳、岳阳、钱光人

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上海大学环境与化学工程学院,上海 200444

飞灰 氯盐 重金属 废水处理 资源化利用

2024

环境保护科学
沈阳环境科学研究院

环境保护科学

CSTPCD
影响因子:0.469
ISSN:1004-6216
年,卷(期):2024.50(6)