Quantitative Analysis of Anisole in Water by Head Space Solid-Phase Microextraction-Gas Chromatography/Mass Spectrometry
A method was established for the determination of trace anisole residues in water by head space solid phase microextraction-gas chromatography-mass spectrometry.The factors affecting the detection results,such as the types of fibers and extraction time,were optimized.Through the optimization of conditions,the linearity of the established method was excellent in the range of 1～1 000 μg/L,the linear correlation coefficient was greater than 0.999.When the spiked concentrations were 10,60 and 300 μg/L,the recoveries were from 85％to 120％,and the relative standard deviations(RSD)were from 3.95％to 6.72％.In the full scanning mode,the detection limit of anisole was 0.3 μg/L.The experimental results show that the method is fast and simple,and the sensitivity,precision and accuracy can meet the requirements for the determination of anisole residues in water.
AnisoleLiquid liquid extractionPurge and trapSolid phase microextractionGas chromatography/mass spectrometry
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维普
