荧光探针PTAID固态试纸法测定土壤中Pd2+和Cu2+的比较研究
A Comparative Study of Pd2+ and Cu2+ in Soil by PTAID and ICP-OES
董铮 1王琳 1田芳 1陆鸿飞2
作者信息
- 1. 江苏省镇江环境监测中心,江苏省镇江土壤特色实验室,江苏 镇江 212000
- 2. 江苏科技大学,江苏 镇江 212003
- 折叠
摘要
将新型荧光探针 PTAID以固态形式用于检测土壤中的钯离子(Pd2+)和铜离子(Cu2+),检出限分别为 0.63 和1.19 μmol/L,说明探针PTAID对Pd2+和Cu2+有很高的灵敏度.通过条件优化实验,说明探针PTAID在pH值为4.0～12.0,反应时间为 0～15 min内可以快速检测Pd2+和Cu2+.对土壤样品中的Pd2+和Cu2+进行检测,该方法与电感耦合等离子体发射光谱法相比,准确度和精密度均较高,具有响应时间短、灵敏度高、选择性好等优点,在土壤重金属检测方面具有广阔的应用前景.
Abstract
A novel fluorescent probe PTAID was successfully used to detect Pd2+ and Cu2+ in soil by solid form.The detection limits of PTAID for Pd2+ and Cu2+ were 0.63 and 1.19 μmol/L,respectively,indicating that the probe PTAID had high sensitivity to Pd2+ and Cu2+.Experiments on condition optimization showed that the probe PTAID can quickly detect Pd2+ and Cu2+ in the range of pH 4.0～12.0 and the reaction time is 0～15 min.Compared with ICP-OES method,it has higher accuracy and precision,and has the advantages of high sensitivity,strong selectivity,fast and strong anti-interference.
关键词
荧光探针PTAID/土壤重金属/钯离子/铜离子/电感耦合等离子体发射光谱Key words
Fluorescent probe PTAID/Heavy metals in soil/Palladium ion/Cupric ion/ICP-OES引用本文复制引用
出版年
2024
NETL
NSTL
万方数据