环境科学与技术2024,Vol.47Issue(1) :111-121.DOI:10.19672/j.cnki.1003-6504.1743.23.338

牡蛎壳粉-木醋液促进市政污泥好氧发酵的腐殖化

The Humification of Municipal Sludge in Aerobic Fermentation Enhanced by Oyster Shell Powder and Wood Vinegar

林泽帅 胡湛波 江凡 郭俊灵 郑榆凯 白元硕
环境科学与技术2024,Vol.47Issue(1) :111-121.DOI:10.19672/j.cnki.1003-6504.1743.23.338

牡蛎壳粉-木醋液促进市政污泥好氧发酵的腐殖化

The Humification of Municipal Sludge in Aerobic Fermentation Enhanced by Oyster Shell Powder and Wood Vinegar

林泽帅 1胡湛波 1江凡 2郭俊灵 1郑榆凯 3白元硕1
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作者信息

  • 1. 广西大学资源环境与材料学院,广西 南宁 530004
  • 2. 自然资源部南方石山地区矿山地质环境修复工程技术创新中心,广西 南宁 530028
  • 3. 华南理工大学环境与能源学院,广东 广州 510006
  • 折叠

摘要

为提高市政污泥传统好氧发酵产品的肥效,该文以市政污泥为原料、稻壳为辅料,通过添加物料总质量15%的牡蛎壳粉(OS组)、添加2%的木醋液(WV组)及联合添加15%的牡蛎壳粉+2%的木醋液(OS-WV组),探究牡蛎壳粉联合木醋液对市政污泥好氧发酵腐殖化进程及其产物肥效的影响.结果表明,OS-WV组可优化堆体理化性质并提高氮磷养分,发酵结束时,OS-WV组发酵产物的 TN、NH4+-N、NO3--N、TP、Olsen-P分别达到 19.15、0.025、0.43、23.89、1.74 mg/g,显著高于其他实验组;OS-WV 组堆体的腐殖化程度更高,胡敏素(HU)向胡敏酸(HA)和富里酸(FA)转化的强度更大.傅里叶红外光谱结果分析表明,联用牡蛎壳粉和木醋液可促使堆体中多糖类物质降解,增加芳构化程度,从而强化了腐殖化过程;三维荧光光谱分析表明,牡蛎壳粉和木醋液在促进生成高分子量和结构复杂的腐殖质(HS)组分方面具有协同作用;经过为期40d的小白菜盆栽实验,验证了 OS-WV组发酵产物的植物促生长效果最佳.15%牡蛎壳粉联合2%木醋液施用于市政污泥好氧发酵堆体,可促进堆体腐殖化进程并提高发酵产物的肥效.

Abstract

In order to improve the fertilizer efficiency of traditional municipal sludge aerobic fermentation products,this paper uses municipal sludge as raw material,rice husk as auxiliary material,by added 15% oyster shell powder(OS group),2% wood vinegar solution(WV group),and combined 15% oyster shell powder+2% wood vinegar solution(OS-WV group),to explore the effects of oyster shell powder combined with wood vinegar on the humification process of municipal sludge aerobic fermentation and the fertilizer efficiency of the product.The results showed that the physicochemical properties of the OS-WV group could be optimized and the nitrogen and phosphorus nutrients increased.At the end of fermentation,TN,NH4+-N,NO3--N,TP and Olsen-P of the fermentation products in the OS-WV group reached 19.15,0.025,0.43,23.89 and 1.74 mg/g,which were significantly higher than those in other groups.In addition,the humification degree of OS-WV group is higher,and the conversion intensity of humin(HU)to humic acid(HA)and fulvic acid(FA)is greater.Fourier transform infrared spectroscopy(FTIR)analysis showed that the combination of oyster shell powder and wood vinegar promoted the degradation of polysaccharides in the pile,enhanced the aromatization degree,and strengthened the humification pathway.Three-dimensional fluorescence spectrum analysis showed that oyster shell powder and wood vinegar had synergistic effect in promoting the formation of humus(HS)components with high molecular weight and complex structure.Finally,after a 40-day potted experiment of Chinese cabbage,it was verified that the fermentation products of OS-WV group had the best growth promotion effect.In conclusion,under the present conditions,the application of oyster shell powder combined with wood vinegar to municipal sludge aerobic fermentation pile can promote the humification process of the pile and improve the fertilizer efficiency of the fermentation product.

关键词

市政污泥/好氧发酵/牡蛎壳粉/木醋液/腐殖化/肥效

Key words

civil sludge/aerobic fermentation/oyster shell powder/wood vinegar/humification/fertilizer efficiency

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基金项目

广西壮族自治区重点研发计划(桂科 AB19110001)

南宁市创新创业领军人才"邕江计划"资助项目(2022015)

出版年

2024
环境科学与技术
湖北省环境科学研究院

环境科学与技术

CSTPCD北大核心
影响因子:0.943
ISSN:1003-6504
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