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油库周缘区地下水烃类污染物示踪研究

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油库周缘区地下水中烃类溯源分析对于查明地下水中烃类污染物来源与保障油库安全具有重要现实意义。文章采用色谱与色谱-质谱方法对油库内外地下水浮油与水样中烃类特征组分进行分析,筛选出全烃色谱指纹、饱和烃二环倍半萜指纹和芳烃萘菲系列指纹特征比值,结合不同结构化合物的分子指纹特征比值对油库内外地下水烃类污染来源进行解析研究。结果表明,油库内外地下水浮油的色谱指纹特征、二环倍半萜系列与芳烃萘菲系列化合物特征比值都具有明显相似性,呈现同一来源特征;星图对比油库内外浮油及地下水中的烃类,上述特征比值也呈现相似性,揭示油库周缘区地下水中烃类污染物与库内浮油及地下水中烃类具有较强的亲缘性。目前对于地下水中油烃污染来源鉴别还缺乏一套明确的对比方法,二环倍半萜与芳烃萘菲系列化合物可以作为可靠的油源鉴别指标,为研究地下水油烃污染来源提供一种分析技术手段。
Tracing of Hydrocarbon Pollutants in Groundwater around Oil Depot
The traceability analysis of hydrocarbons in groundwater around oil depots is of great practical significance for identifying the sources of hydrocarbon pollutants in groundwater and ensuring the safety of oil depots.The article uses chromatography and chromatography-mass spectrometry methods to analyze the hydrocarbon characteristic components in the floating oil and water samples of groundwater inside and outside the oil depot.Total hydrocarbon chromatographic fingerprint,saturated hydrocarbon bicyclic sesquiterpene fingerprint,and aromatic naphthene series fingerprint characteristic ratios are selected,and the molecular fingerprint characteristic ratios of different structural compounds are combined to ana-lyze the sources of hydrocarbon pollution in groundwater inside and outside the oil depot.The results showed that the chro-matographic fingerprint characteristics of groundwater floating oil inside and outside the oil depot,as well as the ratio of the characteristics of bicyclic sesquiterpenes and aromatic naphthalene series compounds,all showed significant similarities,showing the same source characteristics.The star chart compares the hydrocarbons in the floating oil and groundwater inside and outside the oil depot,and the above characteristic ratios also show similarity,revealing a strong affinity between hydrocarbon pollutants in groundwater around the oil depot and hydrocarbons in the floating oil and groundwater inside the depot.At present,there is a lack of a clear comparative method for identifying the sources of oil and hydrocarbon pollution in groundwater.Dicyclic sesquiterpenes and aromatic naphthalene series compounds can serve as reliable oil source identification indicators,providing an analytical technique for studying the sources of oil and hydrocarbon pollution in groundwater.

groundwateroil hydrocarbon pollutionchromatographic fingerprinttracing the sources of pollutantoil depot

王永庆、李洪波、赵红静、王霆

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长江大学油气地球化学与环境湖北省重点实验室,湖北 武汉 430100

油气资源与勘探技术教育部重点实验(长江大学),湖北 武汉 430100

长江大学资源与环境学院,湖北 武汉 430100

地下水 油烃污染 色谱指纹 污染物示踪 油库

油气资源与勘探技术教育部重点实验室(长江大学)青年创新团队项目

PI2021-05

2024

环境科学与技术
湖北省环境科学研究院

环境科学与技术

CSTPCD北大核心
影响因子:0.943
ISSN:1003-6504
年,卷(期):2024.47(2)
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