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大气挥发性有机物受体模型来源解析研究进展

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挥发性有机物(VOCs)是细颗粒物和臭氧的重要前体物,对其开展来源解析研究非常必要。正定矩阵因子分解(PMF)模型是应用较为广泛的受体模型来源解析技术,该文归纳了 PMF模型中关键参数的选取,综述了其在大气VOCs来源解析上的应用情况,总结了中国不同区域VOCs来源特点,阐述了特征比值法、潜在污染源区及传输路径分析方法等方法与PMF模型结合开展VOCs来源的研究进展。结果表明:(1)VOCs物种、不确定度、物种权重、因子数等关键参数的选取均会影响解析结果的误差;(2)大气VOCs来源因地区、季节及人为管控等因素影响而存在差异,但机动车相关排放源是北京市、济南市、武汉市、长三角地区及南部城市大气VOCs的主要来源,贡献在16。9%~75。4%;(3)在PMF模型获取源贡献的基础上,利用条件概率函数、潜在源贡献函数、浓度加权轨迹等模型可掌握污染来源空间分布及传输贡献,光化学损耗估算方法可减小高活性VOCs的解析误差,为管理部门提供更加精准的VOCs污染来源信息。研究显示,在PMF模型广泛应用于大气VOCs来源解析的背景下,开展量化VOCs污染本地生成及区域传输贡献、准确估算VOCs损耗方法研究具有重要意义。
The Research Progress on the Source Apportionment Method of Volatile Organic Compounds in Ambient Air with the Receptor Model
Volatile Organic Compounds(VOCs)are important precursors of fine particulate matter and ozone,so it is neces-sary to perform the source apportionment of VOCs.In this study,the selection of key parameters in Positive Matrix Factoriza-tion(PMF)model analyses was summarized.The application of PMF model in the source apportionment of ambient VOCs,the sources characteristics of VOCs in different regions of China were reviewed.The research progress of VOCs source appor-tionment by combining other methods with PMF models was expounded.The results showed that the result error of VOCs sources apportionment with PMF model would be affected by the selection of key parameters,including VOCs species,uncer-tainty,species weight,factor number.There were different effects on the sources of ambient VOCs,due to the difference of region,season and human control factors.Vehicle-related emission sources were the main source of ambient VOCs in Beijing,Jinan,Wuhan,Yangtze River Delta region and southern cities of China,contributing 16.9%~75.4%.Based on the source contributions obtained by PMF model analysis,CPF,PSCF,CWT could be used to obtain the spatial distribution and transmission contribution of pollution sources,the photochemical loss estimation method of VOCs could reduce the analytical error of highly active VOCs,which would provide more accurate VOCs pollution source information for the management department.In the context that PMF model has been widely used in the source apportionment of ambient VOCs,it is of great significance to investigate the methods of quantifying the local generation and regional transmission contribution of VOCs and accurately estimating VOCs loss concentration.

volatile organic compounds(VOCs)source appointmentreceptor modelPMF model

蔡美全、常淼、丁萌萌、周健楠、沈秀娥、刘保献

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北京市生态环境监测中心,大气颗粒物监测技术北京市重点实验室,北京 100048

挥发性有机物 来源解析 受体模型 正定矩阵因子分解模型

国家重点研发计划

2021YFC1809004

2024

环境科学与技术
湖北省环境科学研究院

环境科学与技术

CSTPCD北大核心
影响因子:0.943
ISSN:1003-6504
年,卷(期):2024.47(2)
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