首页|基于PMF模型和稳定同位素的地下水污染源解析

基于PMF模型和稳定同位素的地下水污染源解析

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识别地下水污染来源、理清污染责任是地下水环境保护工作的重要基础。该研究以珠三角地区某化工园区及其相邻的垃圾填埋场为调查对象,分析了研究区地下水污染分布特征,利用正定矩阵因子分析(PMF)模型和稳定同位素技术,开展了地下水污染溯源解析。结果显示:研究区地下水中pH、NH4+、Fe、Mn均存在不同程度超标,且具有空间异质性,超标最严重点位靠近化工园区与垃圾填埋场交界处,NH4+、Fe、Mn浓度分别为68。20、28。10、15。80 mg/L,超标倍数分别为44。5倍、13。1倍、9。5倍;PMF模型初步揭示了研究区地下水水质影响因子,分别为水文地球化学演化(43。1%)、人为污染作用(27。9%)、原生地质作用(15。7%)。氨氮的氮稳定同位素分析结果进一步明确了人为污染来源,垃圾渗滤液δ15N-NH4+值位于地下水特征值区间且与地下水氨氮超标点位δ15N-NH4+值接近,表明垃圾填埋场是地下水氨氮污染的主要贡献源。通过结合PMF模型与稳定同位素技术,有效识别了地下水污染来源及其贡献率,明确了不同污染源之间的污染责任,为地下水污染防治和环境管理提供科学支撑。
Source Identification of Groundwater Pollution Based on PMF Model and Stable Isotope
Identifying the source of pollution and clarifying the pollution responsibility is an important basis for groundwater environmental protection.In this study,a chemical industry park and its adjacent landfill in the Pearl River Delta region was selected as the investigation object.We characterize the distribution of groundwater pollution,and identify the source of groundwater pollution based on both PMF model and stable isotope technique.The results showed that the detected concen-tration of pH,NH4+,Fe,Mn indicated the groundwater pollution.The most serious point was near the junction between the chemical park and the landfill,in which the concentration of NH4+,Fe,Mn was 68.20,28.10,15.80 mg/L,respectively.The PMF model initially revealed the influencing factors of groundwater quality in the study area,which were hydrogeochemical evolution(43.1%),anthropogenic pollution(27.9%)and primary geological process(15.7%).The δ15N-NH4+value further confirmed the landfill was the main contributor to groundwater ammonia nitrogen pollution.The groundwater pollution sourc-es and contribution rates were effectively identified through the combination of PMF model and stable isotope technology,and the pollution responsibilities among different pollution sources were clarified,providing scientific support for groundwater pollution prevention and environmental management.

groundwatersource of pollutionPMF modelstable isotopesource identification

韩奕彤、罗育池、秘昭旭、刘畅

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广东省环境科学研究院,广东 广州 510045

地下水 污染源 PMF模型 稳定同位素 源解析

广东省省级科技计划项目广东省科技创新战略专项资金项目广东省环境科学研究院科技创新项目

2017B0202360012019B121205004HKYKJ-202203

2024

环境科学与技术
湖北省环境科学研究院

环境科学与技术

CSTPCD北大核心
影响因子:0.943
ISSN:1003-6504
年,卷(期):2024.47(3)